Iron carbonyl cluster-incorporated Cu(I) NHC complexes in homocoupling of arylboronic acids: an effective [TeFe3(CO)9](2-) ligand

Dalton Transactions : an International Journal of Inorganic Chemistry
Chien-Nan LinMinghuey Shieh

Abstract

A new type of TeFe3(CO)9-incorporated dicopper NHC complex was obtained directly from one-pot reactions. By the introduction of the cluster anion [TeFe3(CO)9](2-) and NHCs as the ligands, these di-Cu(i)-based complexes exhibited pronounced catalytic activities toward the homocoupling of arylboronic acids with low Cu loadings and high yields (up to 98%).

References

May 31, 2002·Acta Crystallographica. Section B, Structural Science·Frank H Allen
Dec 20, 2003·The Journal of Organic Chemistry·Ayhan S DemirMustafa Emrullahoglu
Sep 25, 2004·The Journal of Organic Chemistry·Carl F NisingStefan Bräse
Oct 3, 2008·Journal of the American Chemical Society·Minghuey ShiehChih-Chiang Shen
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Oct 8, 2014·Angewandte Chemie·Fabian DielmannManfred Scheer
Mar 10, 2015·Accounts of Chemical Research·Gagik G Melikyan

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Citations

Jul 15, 2021·Chemical Society Reviews·Cristiana CesariLouise A Berben
Apr 3, 2019·Chemical Reviews·Christene A SmithCathleen M Crudden

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