Iron catalysts with N-ligands for carbene transfer of diazo reagents

Chemical Society Reviews
Caterina DamianoEmma Gallo

Abstract

Transition-metal-catalyzed carbene transfer reactions, involving diazo compounds and their precursors, are powerful tools for creating new C-C bonds. Depending on the involved catalytic system, the carbene insertion can efficiently be driven towards a specific functional group for the synthesis of a wide portfolio of fine chemicals. The present report is focused on the catalytic activity of iron catalysts in promoting alkene cyclopropanations, C-H and X-H (X = N, O, S, Se, Si, Sn, Ge) functionalizations. Porphyrin, porphyrinoid and non-heme iron complexes are discussed by analyzing experimental studies and theoretical calculations performed for proposing reaction mechanisms. The catalytic activity of artificial iron biocatalysts is also briefly reported in order to underline the similarities and differences between reaction mechanisms mediated by modified biocatalysts and synthetic catalysts. This review summarizes the achievements made in this field since 2006.

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Citations

Jan 15, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Lucie P CaillerAlexander B Sorokin
Apr 20, 2021·The Journal of Organic Chemistry·Shuai ZhaoXin Chen
Apr 17, 2021·Chemistry : a European Journal·Yubiao HongEric Meggers
Jul 20, 2021·Organic Letters·Feifei He, Rene M Koenigs
Aug 26, 2021·Inorganic Chemistry·Brett M HakeyCarsten Milsmann
Nov 19, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Kuntal Pal, Chandra M R Volla

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Methods Mentioned

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Software Mentioned

Svec

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