Abstract
Three isomeric ionene polymers containing 1,4-diazabicyclo[2.2.2]octane (DABCO) and N,N'-(x-phenylene)dibenzamide (x = ortho-/meta-/para-) linkages have been used as dopant agents to produce n-doped poly(3,4-ethylenedioxythiophene) (PEDOT) electrodes by reducing already dedoped conducting polymer (CP) films. This work focuses on the influence of the ionene topology on both the properties of n-doped PEDOT:ionene electrodes and the success of the in situ thermal gelation of the ionene inside the CP matrix. The highest doping level is reached for the para-isomeric ionene-containing electrode, even though the content of ortho- and meta-topomers in the corresponding n-doped PEDOT:ionene electrodes is greater. Thus, many of the incorporated ionene units are not directly interacting with CP chains and, therefore, they do not play an active role as n-dopant agents but they are crucial for the in situ formation of the ionene hydrogels. The effect of the ionene topology is practically non-existent on properties such as the specific capacitance and wettability of PEDOT:ionene films, and it is small but non-negligible on the electrochemical and thermal stability. In contrast, the surface morphology, topography, and distribution of dopant m...Continue Reading
References
Jan 5, 2002·Journal of the American Chemical Society·Seiji TsuzukiKazutoshi Tanabe
Oct 10, 2002·Journal of the American Chemical Society·Seiji TsuzukiReiko Azumi
Mar 28, 2006·Organic Letters·Yoichi M A Yamada, Yasuhiro Uozumi
Jun 27, 2007·Journal of Computational Chemistry·Francisco Rodríguez-RoperoCarlos Alemán
Aug 21, 2007·Journal of the American Chemical Society·Masaru YoshidaNobutsugu Minami
Feb 19, 2008·The Journal of Physical Chemistry. B·David Zanuy, Carlos Aleman
Aug 7, 2008·Macromolecular Bioscience·Luis J del ValleCarlos Alemán
Jun 12, 2010·Journal of the American Chemical Society·Seelam PrasanthkumarAyyappanpillai Ajayaghosh
Sep 4, 2010·Journal of the American Chemical Society·Seelam PrasanthkumarAyyappanpillai Ajayaghosh
Jul 19, 2013·Journal of Nanoscience and Nanotechnology·Christopher M MacNeillNicole H Levi-Polyachenko
Apr 30, 2014·Journal of Chemical Information and Modeling·Roland G HuberThomas Fox
Nov 29, 2014·Angewandte Chemie·Seelam PrasanthkumarAyyappanpillai Ajayaghosh
Jul 16, 2015·ACS Applied Materials & Interfaces·Thomas M Higgins, Jonathan N Coleman
Nov 21, 2015·Scientific Reports·Yuqing LiuJun Chen
Mar 29, 2016·Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices·Zia Ullah KhanXavier Crispin
Jul 30, 2016·Scientific Reports·Ioannis PetsagkourakisGeorges Hadziioannou
Mar 30, 2017·ACS Applied Materials & Interfaces·Dawei ZhaoHaipeng Yu
Apr 5, 2017·Soft Matter·Jürgen BachlDavid Díaz Díaz
Sep 28, 2017·ACS Applied Materials & Interfaces·Arne StrassburgJoerg C Tiller
Nov 2, 2017·Scientific Reports·Ji-Eun LimHan-Ki Kim
Apr 4, 2018·Physical Chemistry Chemical Physics : PCCP·Maricruz G SaboríoCarlos Alemán
Citations
Jun 3, 2020·Macromolecular Bioscience·Rafał Jerzy KopiaszDominik Jańczewski
Jun 4, 2020·Polymers·Kathryn E O'HarraJason E Bara
Sep 11, 2019·Soft Matter·Margarita Sánchez-JiménezCarlos Alemán
Jan 4, 2021·Journal of Controlled Release : Official Journal of the Controlled Release Society·Anna Puiggalí-JouCarlos Alemán