Keggin Structure, Quō Vādis?

Frontiers in Chemistry
Aleksandar Kondinski, Tatjana N Parac-Vogt

Abstract

Working under the supervisor of William Lawrence Bragg at the University of Manchester and being under the direct personal and scientific influence by Linus Pauling, Dr. James Fargher Keggin some 85 years ago published a highly unique discovery-the structure of phosphotungstic acid (Nature 1933, 131, 908-909). This structure sparked the reports of other related polyanions from Keggin's contemporaries, marking the true beginnings of structural polyoxometalate chemistry. In this perspective article, we unveil some aspects and applications of Keggin's structure and discuss how it has shaped the course of our understanding of polyoxometalate chemistry and nanomolecular metal oxides/hydroxides in general.

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Citations

Jan 3, 2019·Angewandte Chemie·Lucile ChatelainMarinella Mazzanti
Jul 2, 2019·Angewandte Chemie·Archismita MisraMay Nyman
Dec 4, 2019·Chemical Society Reviews·Alexander V AnyushinTatjana N Parac-Vogt
Jan 25, 2020·Physiological Measurement·Julien OsterLionel Tarassenko
Aug 25, 2020·Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials·Sergey V Krivovichev
Apr 25, 2020·Advanced Science·Alexey S CherevanDominik Eder
Jan 13, 2021·Inorganic Chemistry·Shadi DerakhshanradChris Ritchie
Sep 4, 2021·Nanoscale·Aleksandar Kondinski

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Methods Mentioned

BETA
X-ray

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