Abstract
Straightforward access to a new cyanide-bridged {Fe4Co4} "molecular box" containing a potassium ion, namely K⊂{[FeII(Tp)(CN)3]4[CoIII(pzTp)]3[CoII(pzTp)]} (1) (with Tp and pzTp = tris- and tetrakis(pyrazolyl)borate, respectively), is provided, alongside its full characterisation. A detailed analysis of the molecular structure (X-ray diffraction, mass spectrometry, NMR spectroscopy) and electronic properties (EPR spectroscopy, SQUID magnetometry, UV/Vis spectroscopy, cyclic voltammetry) reveals that 1 shows slow magnetic relaxation and a remarkable photomagnetic effect at low temperature which is reminiscent of some FeCo Prussian Blue Analogues (PBAs), and is ascribed to a photo-induced electron transfer. However, in contrast with these inorganic polymers, the overall neutral compound 1 is soluble and remarkably stable in organic solvents such as CH2Cl2. Moreover, 1 shows interesting redox versatility, with electrochemical experiments revealing the possible access to six stable redox states.
References
May 3, 1996·Science·O SatoK Hashimoto
Jan 5, 2002·Chemical Reviews·M. Irie
Mar 4, 2003·Inorganic Chemistry·Jenny Y YangJeffrey R Long
May 28, 2003·Inorganic Chemistry·D Chanaka L De Alwis, Franklin A Schultz
Jun 19, 2003·Angewandte Chemie·Sodio C N HsuThomas B Rauchfuss
Sep 17, 2003·Accounts of Chemical Research·Osamu Sato
Jan 21, 2004·Inorganic Chemistry·Matthew L Kuhlman, Thomas B Rauchfuss
Jan 15, 2005·Angewandte Chemie·Andrea Dei
Sep 29, 2005·Journal of Magnetic Resonance·Stefan Stoll, Arthur Schweiger
Mar 30, 2006·Journal of the American Chemical Society·Dongfeng LiStephen M Holmes
Jan 11, 2007·Angewandte Chemie·Christophe Cartier dit MoulinAnne Bleuzen
Feb 8, 2007·Accounts of Chemical Research·Julie L BoyerThomas B Rauchfuss
Jun 15, 2007·Journal of the American Chemical Society·Eric J SchelterKim R Dunbar
Jun 20, 2008·Inorganic Chemistry·Masayuki NiheiHiroki Oshio
Jul 9, 2008·Inorganic Chemistry·William K MyersDavid L Tierney
Feb 28, 2009·Chemistry : a European Journal·Istemi KuzuFrank Breher
Apr 23, 2010·Angewandte Chemie·Yuanzhu ZhangStephen M Holmes
Jul 31, 2010·Journal of the American Chemical Society·Jean-Daniel CafunAnne Bleuzen
Oct 23, 2010·Chemical Communications : Chem Comm·Julie MercurolMiguel Julve
Feb 24, 2011·Journal of the American Chemical Society·Masayuki NiheiHiroki Oshio
Mar 1, 2011·The Journal of Physical Chemistry. a·Piotr PietrzykArtur Michalak
Sep 10, 2011·Chemistry : a European Journal·Diana SiretanuRodolphe Clérac
May 5, 2012·Angewandte Chemie·Masayuki NiheiHiroki Oshio
Aug 10, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Kiyotaka MitsumotoHiroki Oshio
Sep 12, 2012·Journal of the American Chemical Society·Julia VallejoEmilio Pardo
Jan 17, 2013·Journal of the American Chemical Society·Abhishake MondalRodrigue Lescouëzec
Dec 11, 2013·Chemical Communications : Chem Comm·Li CaoDongfeng Li
Oct 24, 2014·Journal of the American Chemical Society·Yuan-Zhu ZhangStephen M Holmes
Jul 23, 2015·Journal of the American Chemical Society·Valentin V NovikovRichard E P Winpenny
Apr 1, 2016·Chemical Science·Raúl Díaz-TorresNúria Aliaga-Alcalde
Citations
Jul 22, 2018·Chemistry : a European Journal·Emilia KuzniakRobert Podgajny
Oct 27, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Bin XiaJian-Rong Li
May 9, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Maria-Gabriela AlexandruMiguel Julve
Jun 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Gabriela MarinescuMarius Andruh
Nov 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Jedrzej KobylarczykRobert Podgajny
May 15, 2020·Chemical Communications : Chem Comm·Amina BenchohraRodrigue Lescouëzec
Jan 17, 2020·Angewandte Chemie·Juan-Ramón JiménezRodrigue Lescouëzec
Jan 24, 2017·Chemistry : a European Journal·Yoshihiro SekineHiroki Oshio
Nov 2, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·J-R JiménezR Lescouëzec
Aug 7, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Tamires S FernandesDanielle Cangussu
Apr 25, 2018·Chemical Communications : Chem Comm·Juan-Ramón JiménezRodrigue Lescouëzec
Nov 2, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Chunyang ZhengDongfeng Li
Apr 19, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Maria-Gabriela AlexandruMiguel Julve
Jul 26, 2017·Chemistry : a European Journal·Ji-Xiang HuTao Liu
Jan 23, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Prashurya Pritam MudoiNayanmoni Gogoi
Apr 24, 2021·The Journal of Physical Chemistry. a·Sujit KamilyaAbhishake Mondal
Jun 26, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Xin-Hua ZhaoYuan-Zhu Zhang
Jun 22, 2021·Chemical Society Reviews·Wei HuangDayu Wu
Dec 10, 2016·Inorganic Chemistry·Rong-Jia WeiHiroki Oshio
Mar 22, 2019·The Journal of Physical Chemistry Letters·Niéli DafféJan Dreiser
Jan 14, 2020·Inorganic Chemistry·Miguel A GonzálvezManuel Martínez
Aug 18, 2020·Inorganic Chemistry·Sujit KamilyaAbhishake Mondal
Jun 9, 2017·Inorganic Chemistry·Piotr KoniecznyRobert Podgajny
Sep 8, 2021·Inorganic Chemistry·Lingyi MengYuan-Zhu Zhang
Sep 29, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Maria-Gabriela AlexandruMiguel Julve
Nov 10, 2021·Inorganic Chemistry·Prashurya Pritam MudoiNayanmoni Gogoi
Nov 13, 2021·Inorganic Chemistry·Miguel A GonzálvezManuel Martínez