Kinetics and degradation mechanism of tris (1-chloro-2-propyl) phosphate in the UV/H2O2 reaction.

Chemosphere
Yeongjo SonKyung-Duk Zoh

Abstract

Tris (1-chloro-2-propyl) phosphate (TCPP) is a chlorinated organic phosphate used in various applications as a flame retardant and plasticizer. TCPP is a known suspected carcinogen and is not effectively removed by traditional water treatments such as biological, chlorination, and UV irradiation. In this study, the UV/H2O2 reaction was employed to degrade TCPP in water. TCPP was effectively degraded in the UV/H2O2 reaction by pseudofirst-order kinetics. The second-order rate constant of the reaction between the TCPP and OH radical was determined to be 4.35 (±0.13) × 108 M-1 s-1 using the competition kinetics with nitrobenzene as a reference compound. The degradation of TCPP was affected by the amount of H2O2, pH, and coexisting water components such as HCO3-, NO3-, and humic acid. Approximately 64.2% of total organic carbon (TOC) in TCPP was mineralized in 12 h during the UV/H2O2 reaction, whereas chloride (Cl-) and phosphate (PO43-) ions were identified as ionic byproducts with the recoveries of 96% chlorine (Cl) and 50% phosphorus (P). Five organic transformation products (TPs) of TCPP were also identified using LC-qTOF/MS. Considering the identified TPs, the main degradation pathway of TCPP during the UV/H2O2 reaction was fo...Continue Reading

Citations

Apr 1, 2021·Food and Chemical Toxicology : an International Journal Published for the British Industrial Biological Research Association·Yufeng GongViktoryia Kulikouskaya

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.