Largest mixed transition metal/actinide cluster: a bimetallic Mn/Th complex with a [Mn10Th6O22(OH)2]18+ core

Inorganic Chemistry
Abhudaya MishraGeorge Christou

Abstract

A high-nuclearity mixed transition metal/actinide complex has been prepared from the reaction of a Mn(III)4 complex with Th(NO3)4 in MeCN/MeOH. The complex [Th6Mn10O22(OH)2(O2CPh)16(NO3)2-(H2O)8] is the largest such complex to date and the first Th/Mn species. It is rich in oxide groups, which stabilize all of the metals in the high Th(IV) and Mn(IV) oxidation levels. Magnetic characterization establishes that the complex has an S = 3 ground-state spin value.

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Citations

Oct 26, 2012·Chemical Reviews·Jie Qiu, Peter C Burns
Mar 23, 2012·Inorganic Chemistry·Juan DiwuThomas E Albrecht-Schmitt
Feb 11, 2015·The Journal of Physical Chemistry. a·Davide TianaA Martín Pendás
Apr 24, 2010·Chemical Society Reviews·George E KostakisAnnie K Powell
May 11, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Amer BaniodehAnnie K Powell
Oct 13, 2007·Inorganic Chemistry·Anastasios J TasiopoulosGeorge Christou
Mar 11, 2008·Inorganic Chemistry·Xiang-Jian KongLan-Sun Zheng
Dec 2, 2014·Inorganic Chemistry·Jie LingPeter C Burns

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