Late stage modifications of P-containing ligands using transition-metal-catalysed C-H bond functionalisation

Chemical Communications : Chem Comm
Zhuan ZhangJean-François Soulé

Abstract

Phosphorus containing molecules have seen widespread applications in the development of innovative metal-ligand catalysts and materials. In recent years, the implementation of late-stage modifications of phosphorus derivatives via ortho-regioselective C-H bond functionalisation has led to faster and better ways for the synthesis of complex ligands by creating new reactions with low impact on the environment. This Feature article highlights transition-metal catalysed regioselective C-H bond functionalisation of phosphorus-containing molecules, in which the phosphorus containing unit plays the role of a directing group for C-H bond activation and the synthesis of new functional phosphorus derivatives.

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Citations

Jan 8, 2019·Angewandte Chemie·Jian WenZhuangzhi Shi
Jan 22, 2019·Angewandte Chemie·Kazuishi FukudaJun Takaya
Aug 2, 2019·Angewandte Chemie·Jompol ThongpaenOlivier Baslé
Jan 10, 2020·Chemical Communications : Chem Comm·Shang-Zheng SunHui-Xiong Dai
Feb 6, 2020·Chemistry : a European Journal·Guang-Ao YuChang-Duo Yue
Dec 10, 2019·Angewandte Chemie·Olivier BasléRomane Manguin
Nov 12, 2020·Chemical Communications : Chem Comm·Yuan NiuShangdong Yang
Feb 26, 2021·Chemical Society Reviews·Bin Li, Pierre H Dixneuf
Apr 9, 2019·Organic Letters·Jia-Wei LiMing-Hua Zeng
Dec 9, 2021·Chemistry : a European Journal·Jiahang LvZhuangzhi Shi

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Methods Mentioned

BETA
X-ray
amidation

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