Lewis-acid induced disaggregation of dimeric arylantimony oxides

Chemical Communications : Chem Comm
Ralf KatherJens Beckmann

Abstract

The previously known dimeric arylantimony oxides (Ph3SbO)2 and [2,6-(Me2NCH2)2C6H3SbO]2 were disaggregated by the Lewis acid B(C6F5)3 giving rise to the formation of the Lewis pair complexes Ph3SbOB(C6F5)3 and 2,6-(Me2NCH2)2C6H3SbOB(C6F5)3 having short bipolar single Sb-O bonds.

References

Jun 28, 2001·Journal of the American Chemical Society·Y Matano, H Nomura
Nov 16, 2002·Angewandte Chemie·Dante NeculaiDietmar Stalke
Nov 14, 2008·Angewandte Chemie·Jens BeckmannBurkhard Wettig
Oct 18, 2011·Journal of the American Chemical Society·Rajendra S GhadwalGernot Frenking
Dec 14, 2011·Journal of Computational Chemistry·Tian Lu, Feiwu Chen
Oct 23, 2012·Journal of Molecular Graphics & Modelling·Tian Lu, Feiwu Chen
Nov 19, 2013·Angewandte Chemie·Daniel HimmelAndreas Schnepf
May 23, 2014·Angewandte Chemie·Gernot Frenking
Jun 4, 2014·Angewandte Chemie·Daniel HimmelAndreas Schnepf

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Citations

Jun 2, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jan VránaLibor Dostál
Aug 11, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Chang-Hong Chen, François P Gabbaï
Apr 4, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Marian OlaruJens Beckmann
Mar 13, 2019·Chemistry : a European Journal·Vít KremláčekLibor Dostál
Mar 11, 2021·Chemical Communications : Chem Comm·John S Wenger, Timothy C Johnstone

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