Ligand and electronic-structure effects in metal-mediated gas-phase activation of methane: a cold approach to a hot problem

Dalton Transactions : an International Journal of Inorganic Chemistry
Maria Schlangen, Helmut Schwarz

Abstract

Gas-phase ion-molecule reactions, complemented by DFT and wave-function based electronic structure calculations, are presented, which permit rather detailed descriptions of two fundamental processes related to the activation of methane at room temperature. (i) Recent examples are discussed, which shed light on the role of oxygen-centered radicals in the first step of the oxidative dimerization of methane, i.e. the homolytic C-H bond cleavage of methane. (ii) Thermal ligand exchange processes of the type ML(+) + CH(4) --> M(CH(3))(+) + LH are analyzed in detail with an emphasis on L = H and F attached to various transition-metal cations M(+). It will be demonstrated inter alia that similar systems, e.g. MH(+) (M = Ni, Pd, Pt) in their room-temperature reactions with methane, actually exhibit fundamentally different mechanistic scenarios.

References

Apr 11, 2000·Accounts of Chemical Research·D SchröderH Schwarz
Jun 8, 2001·Journal of the American Chemical Society·X G ZhangP B Armentrout
Dec 26, 2001·Chemical Reviews·S Niu, M B Hall
Dec 19, 1996·Chemical Reviews·Chris Hall, Robin N. Perutz
May 31, 2002·Nature·Jay A Labinger, John E Bercaw
Jun 6, 2003·Journal of the American Chemical Society·Dina R JustesA Welford Castleman
Oct 22, 2003·Accounts of Chemical Research·Roald HoffmannPhilippe C Hiberty
Jan 6, 2004·Inorganic Chemistry·Marcus LundbergPer E M Siegbahn
Mar 22, 2005·Angewandte Chemie·Diethard K Böhme, Helmut Schwarz
May 20, 2005·Philosophical Transactions. Series A, Mathematical, Physical, and Engineering Sciences·C R A CatlowJ M Thomas
Jun 9, 2005·Chemical Reviews·Martin Lersch, Mats Tilset
Dec 3, 2005·Journal of Computational Chemistry·Ivan RivaltaEmilia Sicilia
Feb 24, 2006·The Journal of Physical Chemistry. B·Nelly A MooreA W Castleman
May 27, 2006·Angewandte Chemie·Sandra FeyelHelmut Schwarz
Jul 21, 2006·The Journal of Physical Chemistry. B·Rustam Z KhaliullinMartin Head-Gordon
Jul 22, 2006·Angewandte Chemie·Detlef Schröder, Jana Roithová
Jul 25, 2006·Chemical Society Reviews·Barry K Carpenter
Sep 21, 2006·Angewandte Chemie·Keith M Gligorich, Matthew S Sigman
Jan 3, 2007·Physical Chemistry Chemical Physics : PCCP·Jeremy N Harvey
Apr 12, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Kallol RayFrank Neese
May 10, 2007·Accounts of Chemical Research·Sason ShaikDevesh Kumar
May 22, 2007·Angewandte Chemie·Maria Schlangen, Helmut Schwarz
May 25, 2007·Mass Spectrometry Reviews·Knut R Asmis, Joachim Sauer
Jan 11, 1991·Science·P B Armentrout
Jul 13, 1990·Science·S T Ceyer
May 3, 2008·The Journal of Physical Chemistry. a·Grant E JohnsonA W Castleman
Aug 9, 2008·Proceedings of the National Academy of Sciences of the United States of America·Grant E JohnsonA W Castleman
Sep 25, 2008·Journal of the American Chemical Society·Grant E JohnsonA W Castleman
Oct 29, 2008·Proceedings of the National Academy of Sciences of the United States of America·Detlef Schröder, Helmut Schwarz
Mar 18, 2009·Chemistry : a European Journal·Giulia de PetrisOrnella Ursini
Mar 19, 2009·Chemical Communications : Chem Comm·David BalcellsOdile Eisenstein
Apr 2, 2009·Journal of the American Chemical Society·Grant E JohnsonA W Castleman
Apr 18, 2009·The Journal of Physical Chemistry. a·Alireza ShayestehDiethard K Bohme
May 29, 2009·Angewandte Chemie·Nicolas DietlHelmut Schwarz
Aug 1, 2009·Nature Chemistry·Robert H Crabtree

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Citations

Oct 25, 2011·Accounts of Chemical Research·Xun-Lei DingSheng-Gui He
Jul 13, 2011·Inorganic Chemistry·Cameron A LippertJake D Soper
Apr 18, 2014·The Journal of Physical Chemistry. a·Abdulkadir KocakRicardo B Metz
Mar 15, 2013·The Journal of Physical Chemistry. a·Gavin W Roffe, Hazel Cox
May 13, 2011·Journal of the American Chemical Society·Daniel SerraPeter Chen
Aug 16, 2012·The Journal of Physical Chemistry. a·Alexandra TsybizovaTibor András Rokob
Mar 3, 2012·The Journal of Physical Chemistry. a·Lianming ZhaoWenyue Guo
Oct 22, 2016·Journal of the American Society for Mass Spectrometry·Kathryn M Davis, Abraham K Badu-Tawiah
Jun 22, 2011·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Xun-Lei DingSheng-Gui He
Mar 13, 2014·Chemistry : a European Journal·Zi-Yu LiSheng-Gui He
Sep 11, 2010·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Oier LakuntzaJesus M Ugalde
Jan 16, 2010·Angewandte Chemie·Detlef Schröder
Apr 14, 2010·International Journal of Molecular Sciences·Heidi Halbwirth
Apr 28, 2011·Physical Chemistry Chemical Physics : PCCP·Yan-Xia ZhaoWei-Jun Zheng
Nov 30, 2019·Physical Chemistry Chemical Physics : PCCP·Emily E Claveau, Evangelos Miliordos
Feb 18, 2011·Chemistry : a European Journal·Zhe-Chen WangSheng-Gui He
Jun 10, 2011·Angewandte Chemie·Helmut Schwarz
Mar 4, 2011·Chemistry : a European Journal·Robert KretschmerHelmut Schwarz
Jan 6, 2011·Physical Chemistry Chemical Physics : PCCP·Yan-Xia ZhaoXun-Lei Ding
Jul 28, 2012·Chemistry : a European Journal·Xiao-Na LiSheng-Gui He
Jan 29, 2011·Chemistry : a European Journal·Nicolas DietlHelmut Schwarz
Jun 22, 2012·Nature Chemistry·Markus G ScheibelSven Schneider
Jun 20, 2015·Angewandte Chemie·Helmut Schwarz
Jan 11, 2016·Chemistry : a European Journal·Davide CorintiSimonetta Fornarini
Nov 10, 2013·Chemical Communications : Chem Comm·Matthias MüllerHolger F Bettinger

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