Ln16 ] complexes (Ln = GdIII , DyIII ): molecular analogues of natural minerals such as hydrotalcite

Dalton Transactions : an International Journal of Inorganic Chemistry
Paul RichardsonPo-Heng Lin

Abstract

Two new hexadecanuclear lanthanide complexes employing the 1,5-bis(salicylidene)carbohydrazide (H2bsc) ligand are reported herein. These polynuclear aggregates crystallize in the R3[combining macron] space group, which is unprecedented in a family of lanthanide complexes with such high nuclearity. Magnetic susceptibility measurements reveal weak intramolecular interactions between the magnetic centres, and in the case of compound 2 (DyIII), single-molecule magnet properties are observed.

References

Nov 20, 2002·Accounts of Chemical Research·S Russell Seidel, Peter J Stang
Jul 17, 2003·Journal of the American Chemical Society·Naoto IshikawaYoukoh Kaizu
Jan 20, 2005·Chemistry : a European Journal·David CasanovaSantiago Alvarez
Sep 28, 2005·Angewandte Chemie·Muralee MurugesuAnnie K Powell
Feb 21, 2007·Journal of the American Chemical Society·Constantinos J MiliosEuan K Brechin
Nov 7, 2008·Inorganic Chemistry·Yan-Zhen ZhengAnnie K Powell
Sep 30, 2010·Chemical Society Reviews·Ulrich Schubert
Oct 5, 2010·Inorganic Chemistry·Yong-Fei ZengE C Sañudo
Apr 19, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Santiago Reinoso
Oct 1, 2011·Chemical Communications : Chem Comm·Iurii L MalaesteanPaul Kögerler
Apr 5, 2013·Chemical Reviews·Daniel N WoodruffRichard A Layfield
Jul 25, 2013·Nature Chemistry·Robin J BlaggRichard E P Winpenny
Jul 31, 2013·Inorganic Chemistry·Sui-Jun LiuXian-He Bu
May 9, 2014·Chemistry : a European Journal·José J BaldovíGuillermo Mínguez Espallargas
May 13, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Eleni C MazarakiotiTheocharis C Stamatatos
Dec 17, 2014·Journal of the American Chemical Society·Jun-Bo PengLan-Sun Zheng
Oct 26, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Rebecca J HolmbergPo-Heng Lin
Nov 1, 2016·Nature Materials·Dennis SheberlaMircea Dincă
Jan 12, 2017·Journal of the American Chemical Society·Katie L M HarrimanMuralee Murugesu
Feb 6, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·T LacelleM Murugesu
Jun 7, 2017·Angewandte Chemie·Fu-Sheng GuoRichard A Layfield
Aug 25, 2017·Nature·Conrad A P GoodwinDavid P Mills
Sep 2, 2017·Chemistry, an Asian Journal·Jingjing LuJinkui Tang

❮ Previous
Next ❯

Citations

Apr 18, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Sourav BiswasVadapalli Chandrasekhar
Jul 3, 2019·Chemical Communications : Chem Comm·Kaitlynn M AyersGaël Ung
Nov 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhi-Rong LuoFu-Pei Liang
Sep 10, 2020·Advanced Materials·Liang FengHong-Cai Zhou
Nov 15, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Li-Wei ChengPo-Heng Lin
Jan 5, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Haiquan TianJianmin Dou

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray

Software Mentioned

SHAPE

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.