Ln(III) methyl and methylidene complexes stabilized by a bulky hydrotris(pyrazolyl)borate ligand

Chemical Communications : Chem Comm
Melanie ZimmermannReiner Anwander

Abstract

The reaction of Ln(AlMe(4))(3) with bulky hydrotris(pyrazolyl)borate (Tp(t)(Bu,Me))H proceeds via a sequence of methane elimination and C-H bond activation, affording unprecedented rare-earth metal ligand moieties including Ln(Me)[(micro-Me)AlMe(3)] and X-ray structurally characterized "Tebbe-like" Ln[(micro-CH(2))(2)AlMe(2)].

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Citations

Nov 11, 2008·Chemical Communications : Chem Comm·Peng CuiJie Sun
Jun 3, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·David P MillsStephen T Liddle
May 8, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Ajay VenugopalNorbert W Mitzel
Jul 16, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Rannveig LitlabøReiner Anwander
Jun 30, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Peng CuiMaxim V Borzov
Sep 30, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Dorothea SchädleReiner Anwander
Sep 13, 2008·Chemistry : a European Journal·Laura C H GerberReiner Anwander
Mar 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jianquan HongLixin Zhang
Oct 31, 2008·Angewandte Chemie·Rannveig LitlabøReiner Anwander
Apr 6, 2013·Chemistry : a European Journal·Oliver J CooperStephen T Liddle
Apr 20, 2011·Chemistry : a European Journal·Daniel BojerNorbert W Mitzel
Aug 10, 2013·The Journal of Pharmacy and Pharmacology·Carmela SaturninoGino Paolucci
Oct 18, 2013·Angewandte Chemie·Christoph SchädleReiner Anwander
Jan 8, 2014·Angewandte Chemie·Jochen Kratsch, Peter W Roesky
Oct 7, 2014·Chemistry : a European Journal·Shihui LiDongmei Cui
Nov 12, 2014·Angewandte Chemie·Polly L ArnoldFritz E Kühn
Nov 14, 2014·Chemistry : a European Journal·Dorothea SchädleReiner Anwander
Nov 13, 2010·Chemical Communications : Chem Comm·Erli LuGuangyu Li
Aug 7, 2016·Chemistry : a European Journal·Nicole DettenriederReiner Anwander
Mar 31, 2011·Journal of the American Chemical Society·Wen-Xiong ZhangZhaomin Hou
Sep 7, 2019·Chemistry : a European Journal·Reiner AnwanderCäcilia Maichle-Mössmer
Dec 12, 2020·Chemical Communications : Chem Comm·Markus M KatzenmayerReiner Anwander
Dec 25, 2010·Inorganic Chemistry·Wenliang HuangPaula L Diaconescu
Jul 10, 2009·Inorganic Chemistry·Andrew V PawlikowskiAaron D Sadow
Jun 8, 2021·Chemical Communications : Chem Comm·Peng DengJianhua Cheng
Oct 1, 2010·Chemical Reviews·Melanie Zimmermann, Reiner Anwander

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