Long-range molecular organization of an organic monolayer grafted on a mineral substrate

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
Bernd StruthFrançois Rieutord

Abstract

Structured and functional materials are of the utmost importance for the development of microelectronic technology. We report on a method to obtain a highly ordered organic molecular layer on a mineral substrate. We took advantage of the regular array of reactive sites present at the single-crystal surface of topaz to perform a liquid-phase silanization reaction. The grazing-incidence diffraction technique was used to characterize the bare and covalently coated surfaces. The ordering of the monomolecular organic layer reproduces the perfect single-crystal structure of the cleaved surface over millimeter distances.

References

Apr 15, 1992·Physical Review. B, Condensed Matter·G RenaudB S Freer
Jun 18, 2003·Analytical and Bioanalytical Chemistry·B StruthO Konovalov
Jan 8, 2004·Journal of the American Chemical Society·Michael P StewartJames M Tour
Feb 8, 2005·Angewandte Chemie·R John ErringtonSamson N Patole
Feb 24, 2005·Journal of the American Chemical Society·Qiao-Yu SunErnst J R Sudhölter
Jul 27, 2005·Langmuir : the ACS Journal of Surfaces and Colloids·Lutz WiegartPierre Terech

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Citations

May 21, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·P Terech
Feb 23, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Sandrine DourdainPierre Terech

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