Low-dimensional porous coordination polymers based on 1,2-bis(4-pyridyl)hydrazine: from structure diversity to ultrahigh CO2/CH4 selectivity

Inorganic Chemistry
Xiao-Min LiuXiao-Ming Chen

Abstract

Solvothermal reactions of metal salts, benzenedicarboxylic acids, and 4,4'-azopyridine (azpy) in different conditions produced four coordination polymers, namely, [Zn(3)(bdc)(3)(bphy)(3)]·2DMF·10H(2)O (3; H(2)bdc = 1,4-benzenedicarboxylic acid, bphy = 1,2-bis(4-pyridyl)hydrazine, and DMF = N,N-dimethylformamide), [Ni(bdc)(bphy)]·DMF·3.5H(2)O (4), [Zn(nipa)(bphy)]·EtOH (5; H(2)nipa = 5-nitroisophthalic acid), and [CoBr(bdc)(0.5)(bphy)]·2DMA·H(2)O (6; DMA = N,N-dimethylacetamide), in which the azpy ligand was in situ reduced. Structural determination reveals that 3-5 consist of the same metal/ligand ratio and similar coordination modes, as well as similar two-dimensional square-grid networks, but differ from their packing/interpenetration modes. 3 consists of alternately arranged single layers and interweaved double layers. Single layers in 4 directly stack in an offset fashion, while 5 is constructed of interdigitated double layers. 6 is a one-dimensional ladderlike structure, which could be regarded as that half of the bridging benzenedicarboxylate ligands in 3-5 are replaced by monodentate bromide ions. Interestingly, the crystal structures of these low-dimensional coordination polymers contain considerable solvent-accessible ...Continue Reading

References

Apr 29, 2004·Angewandte Chemie·Susumu KitagawaShin-ichiro Noro
Jan 27, 2005·Chemical Society Reviews·Susumu Kitagawa, Kazuhiro Uemura
Feb 24, 2007·Angewandte Chemie·Shengqian MaHong-Cai Zhou
Dec 25, 2007·Journal of the American Chemical Society·Krista S WaltonRandall Q Snurr
Jun 3, 2008·Journal of the American Chemical Society·Hye Jin ChoiJeffrey R Long
Jan 1, 2010·Journal of the American Chemical Society·Zhigang XieWenbin Lin
Apr 17, 2010·Chemistry : a European Journal·Aude Demessence, Jeffrey R Long
Sep 17, 2010·Inorganic Chemistry·Atsushi KondoHirofumi Kanoh
Oct 5, 2010·Chemical Communications : Chem Comm·Zhao JinGuang-Shan Zhu
Oct 29, 2010·Nature Communications·Takashi UemuraSusumu Kitagawa
Nov 3, 2010·Chemical Communications : Chem Comm·Yasutaka InubushiSusumu Kitagawa
Nov 6, 2010·Chemical Communications : Chem Comm·Jingming ZhangJing Li
Jan 27, 2011·Nature Communications·Yohei TakashimaSusumu Kitagawa
Mar 3, 2011·Chemical Communications : Chem Comm·Jie-Peng ZhangXiao-Ming Chen
May 4, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Yan ChengHirofumi Kanoh
May 4, 2011·Journal of the American Chemical Society·Hasan K ArslanChristof Wöll
Jul 7, 2011·Advanced Materials·Daqiang YuanHong-Cai Zhou
Jul 27, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao-Min LiuXiao-Ming Chen
Aug 26, 2011·Journal of the American Chemical Society·Yabing HeBanglin Chen
Nov 9, 2011·Journal of the American Chemical Society·Xiao-Ping ZhouDan Li

❮ Previous
Next ❯

Citations

Jun 20, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Huanzhi LiZhiming Duan
Jun 12, 2014·Chemical Reviews·Lucia CarlucciVladislav A Blatov

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.