Low-valent iron(i) amido olefin complexes as promotors for dehydrogenation reactions

Angewandte Chemie
Crispin LichtenbergHansjörg Grützmacher

Abstract

Fe(I) compounds including hydrogenases show remarkable properties and reactivities. Several iron(I) complexes have been established in stoichiometric reactions as model compounds for N2 or CO2 activation. The development of well-defined iron(I) complexes for catalytic transformations remains a challenge. The few examples include cross-coupling reactions, hydrogenations of terminal olefins, and azide functionalizations. Here the syntheses and properties of bimetallic complexes [MFe(I) (trop2 dae)(solv)] (M=Na, solv=3 thf; M=Li, solv=2 Et2 O; trop=5H-dibenzo[a,d]cyclo-hepten-5-yl, dae=(N-CH2 -CH2 -N) with a d(7) Fe low-spin valence-electron configuration are reported. Both compounds promote the dehydrogenation of N,N-dimethylaminoborane, and the former is a precatalyst for the dehydrogenative alcoholysis of silanes. No indications for heterogeneous catalyses were found. High activities and complete conversions were observed particularly with [NaFe(I) (trop2 dae)(thf)3 ].

References

Sep 13, 2001·Journal of the American Chemical Society·J M SmithP L Holland
Sep 4, 2003·Journal of the American Chemical Society·Theodore A Betley, Jonas C Peters
Dec 22, 2004·Angewandte Chemie·Dmitry Bravo-ZhivotovskiiYitzhak Apeloig
Apr 26, 2005·Inorganic Chemistry·Eric J HawrelakPaul J Chirik
Jan 19, 2006·Journal of the American Chemical Society·Jeremy M SmithPatrick L Holland
Feb 17, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Guangcai BaiDouglas W Stephan
Jul 18, 2006·Inorganic Chemistry·Ying YuPatrick L Holland
Nov 9, 2006·Proceedings of the National Academy of Sciences of the United States of America·Michael P HendrichJonas C Peters
Jan 4, 2007·Journal of the American Chemical Society·Connie C LuJonas C Peters
Jan 5, 2008·Inorganic Chemistry·Jennifer ScottPeter H M Budzelaar
Feb 16, 2008·Inorganic Chemistry·Michael T MockCharles G Riordan
Feb 29, 2008·Angewandte Chemie·Carola VogelKarsten Meyer
May 1, 2008·Journal of the American Chemical Society·Ying YuPatrick L Holland
Mar 5, 2010·Journal of the American Chemical Society·Neal P MankadJonas C Peters
Mar 25, 2010·Angewandte Chemie·Ben ConwayJoaquin García Alvarez
Jul 3, 2010·Journal of the American Chemical Society·Yumiko NakajimaFumiyuki Ozawa
Aug 3, 2010·Chemical Reviews·Anne StaubitzIan Manners
Aug 3, 2010·Chemical Reviews·Anne StaubitzIan Manners
Aug 20, 2010·Angewandte Chemie·Gilles Alcaraz, Sylviane Sabo-Etienne
Feb 24, 2011·Angewandte Chemie·Marc-Etienne Moret, Jonas C Peters
Mar 8, 2011·Journal of the American Chemical Society·Yunho Lee, Jonas C Peters
Oct 1, 2011·Journal of the American Chemical Society·Yunho LeeJonas C Peters
Mar 1, 2012·Angewandte Chemie·Karen P ChiangPatrick L Holland
Jun 15, 2012·Journal of the American Chemical Society·Christopher J AdamsJoshua Nunn
Jul 24, 2012·Angewandte Chemie·Meghan M RodriguezPatrick L Holland
Oct 11, 2012·Journal of the American Chemical Society·Wesley Sattler, Gerard Parkin
Dec 12, 2012·Angewandte Chemie·Robin B BedfordJoshua Nunn
Mar 21, 2013·Nature Chemistry·Rafael E Rodríguez-LugoHansjörg Grützmacher
Mar 23, 2013·Angewandte Chemie·Arnab RitJun Okuda
Jun 22, 2013·Nature Chemistry·Joseph M ZadroznyJeffrey R Long
Sep 4, 2013·Organometallics·Henry FongJonas C Peters
Sep 6, 2013·Inorganic Chemistry·Roman M DavydovPatrick L Holland
Dec 20, 2013·Journal of the American Chemical Society·Sidney E Creutz, Jonas C Peters
Jan 1, 2014·Chemical Science·Karen P ChiangPatrick L Holland
Feb 18, 2014·Journal of the American Chemical Society·James R VanceIan Manners
Mar 15, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Ya-Fan LinFumiyuki Ozawa
Apr 23, 2014·Angewandte Chemie·John S Anderson, Jonas C Peters
Jun 24, 2014·Angewandte Chemie·Gaël UngJonas C Peters

❮ Previous
Next ❯

Citations

Sep 22, 2016·Chemistry : a European Journal·Stefan PeltiesRobert Wolf
Jun 15, 2017·Journal of the American Chemical Society·Demyan E ProkopchukMichael T Mock
Oct 19, 2017·Macromolecular Rapid Communications·Chuanyang LiDongmei Cui
Dec 10, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Van An DuIan Manners
Jul 30, 2015·Chemical Communications : Chem Comm·C LichtenbergH Grützmacher
Nov 1, 2018·Chemistry : a European Journal·Thomas M MaierRobert Wolf
Sep 15, 2017·Angewandte Chemie·Montaha H AnjassCarsten Streb
Mar 3, 2018·Israel Journal of Chemistry·Nathan T Coles, Ruth L Webster
May 22, 2018·Chemical Science·Titel JurcaIan Manners
Dec 17, 2020·Chemistry : a European Journal·Anna HanftCrispin Lichtenberg
Jun 25, 2021·Chemical Science·Xiaofang ZhaiWenguang Wang
Jul 29, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Ruth WellerC Gunnar Werncke
Jun 6, 2017·Journal of Chemical Theory and Computation·Jonny Proppe, Markus Reiher

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

The Journal of Organic Chemistry
Carsten Bolm
Proceedings of the National Academy of Sciences of the United States of America
Manuel PérezDouglas W Stephan
© 2021 Meta ULC. All rights reserved