Magnetic behavior and Mossbauer spectra of spin-crossover pyrazolate bridged dinuclear diiron(II) complexes: X-ray structures of high-spin and low-spin [(Fe(NCBH3)(py))2(mu-bpypz)2

Dalton Transactions : an International Journal of Inorganic Chemistry
Keisaku NakanoSumio Kaizaki

Abstract

The synthesis and characterization of new spin-crossover pyrazolato bridged dinuclear [(FeII(NCS)(py))2(mu-bpypz)2] and the corresponding cyanotrihydroborato-kappaN complexes are described together with the X-ray crystal analysis of the latter in both the high-spin and low-spin states as well as the variable temperature magnetic susceptibility and/or Mossbauer spectra demonstrating the spin-crossover which exhibits an one-step process, but not a two-step one characteristic of the known bpym bridged dinuclear complexes.

References

Aug 5, 2000·Chemistry : a European Journal·L CapesO Kahn
Dec 3, 2002·Science·Gregory J HalderJohn D Cashion

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Citations

Oct 15, 2011·Inorganic Chemistry·Ekaterina M ZuevaSerguei A Borshch
Jan 1, 2009·Acta Crystallographica. Section E, Structure Reports Online·Da-Jing XieDun-Ru Zhu
Jan 6, 2012·Acta Crystallographica. Section E, Structure Reports Online·Akio MishimaSatoshi Kawata
Jun 10, 2016·Inorganic Chemistry·Alejandra ArroyaveMichael Shatruk
Feb 28, 2009·Chemistry : a European Journal·Jean-François LétardSumio Kaizaki
Jun 16, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Jośe Antonio RealM Carmen Muñoz
Sep 4, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Sally Brooker, Jonathan A Kitchen
Mar 5, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·A KaibaP Guionneau
Aug 15, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Hayley S ScottKeith S Murray
Oct 12, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Rosanna J ArcherPaul E Kruger
Sep 26, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Takuya ShigaHiroki Oshio
Aug 24, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Galina S MatouzenkoAzzedine Bousseksou
Jan 29, 2011·Inorganic Chemistry·Ekaterina M ZuevaSerguei A Borshch
Nov 8, 2017·Inorganic Chemistry·Santiago Rodríguez-Jiménez, Sally Brooker
May 17, 2018·Inorganic Chemistry·Santiago Rodríguez-JiménezSally Brooker
Sep 1, 2018·Journal of the American Chemical Society·Miguel Paez-EspejoKamel Boukheddaden

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