Manganese(III) and manganese(IV) as chemiluminescence reagents: a review

Analytica Chimica Acta
Allyson J BrownNeil W Barnett

Abstract

Although potassium permanganate [Mn(VII)] has been used extensively as a chemiluminescence reagent for many decades, other manganese-based oxidants have only recently been explored for this purpose. There is strong evidence to suggest that, like permanganate, manganese(III) and manganese(IV) oxidants react with many molecules to produce an excited manganese(II) species that emits light. However, these reagents differ markedly in terms of selectivity, and possess characteristics that provide new avenues for detection, such as the immobilisation of solid manganese dioxide, the production of 'soluble' manganese(IV) nanoparticles, and the electrochemical generation of manganese(III). In this review we examine the emergence of these alternative manganese oxidants as chemiluminescence reagents.

References

Feb 3, 2005·Luminescence : the Journal of Biological and Chemical Luminescence·Jianxiu DuJiuru Lu
Sep 1, 2005·Luminescence : the Journal of Biological and Chemical Luminescence·Fei NieJianxiu Du
Oct 2, 2007·Analytica Chimica Acta·Jacqui L AdcockNeil W Barnett
Oct 31, 2008·Talanta·T J Pastor, F T Pastor

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Citations

Mar 11, 2010·Analytical Sciences : the International Journal of the Japan Society for Analytical Chemistry·Amir WaseemAbdul Nabi
Mar 31, 2012·Drug Testing and Analysis·Brendan J HollandXavier A Conlan
Apr 17, 2012·Journal of the Science of Food and Agriculture·Zhixiang XuHaihua Chen
Sep 17, 2014·Luminescence : the Journal of Biological and Chemical Luminescence·Jean-Paul OtamongaRoger A Jewsbury
Sep 30, 2014·Analytica Chimica Acta·Jacqui L AdcockPaul S Francis
Apr 27, 2019·Luminescence : the Journal of Biological and Chemical Luminescence·Hongjie SongYi Lv
Dec 15, 2010·Drug Testing and Analysis·Jacqui L AdcockPaul S Francis
Apr 9, 2010·Analytical Chemistry·Christopher M HindsonNeil W Barnett
Jul 8, 2011·Analytical Chemistry·Geoffrey P McDermottPaul S Francis
Sep 8, 2009·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Hanwen SunFei Wang

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