Manipulating Ion Migration for Highly Stable Light-Emitting Diodes with Single-Crystalline Organometal Halide Perovskite Microplatelets

ACS Nano
Mingming ChenZhibin Yu

Abstract

Ion migration has been commonly observed as a detrimental phenomenon in organometal halide perovskite semiconductors, causing the measurement hysteresis in solar cells and ultrashort operation lifetimes in light-emitting diodes. In this work, ion migration is utilized for the formation of a p-i-n junction at ambient temperature in single-crystalline organometal halide perovskites. The junction is subsequently stabilized by quenching the ionic movement at a low temperature. Such a strategy of manipulating the ion migration has led to efficient single-crystalline light-emitting diodes that emit 2.3 eV photons starting at 1.8 V and sustain a continuous operation for 54 h at ∼5000 cd m-2 without degradation of brightness. In addition, a whispering-gallery-mode cavity and exciton-exciton interaction in the perovskite microplatelets have both been observed that can be potentially useful for achieving electrically driven laser diodes based on single-crystalline organometal halide perovskite semiconductors.

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Citations

Apr 4, 2018·Advanced Materials·Yusheng LeiSheng Xu
Nov 2, 2019·Journal of Colloid and Interface Science·Wenjihao HuHongbo Zeng
Jun 18, 2021·ACS Nano·Amrita DeyLakshminarayana Polavarapu
Aug 6, 2021·ACS Applied Materials & Interfaces·Shanshan YanKar Wei Ng
Oct 27, 2017·Journal of the American Chemical Society·Yan-Fang ChenDario M Bassani

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