Measurement of the field-free alignment of diatomic molecules

The Journal of Physical Chemistry. a
Nan XuQihuang Gong

Abstract

An apparatus was constructed to experimentally quantify the field-free alignment of diatomic molecules irradiated by strong femtosecond laser pulses. In this apparatus, both homodyne and pure heterodyne detections were realized. The alignment signal is proportional to [<cos(2)theta> - 1/3](2) for homodyne detection and (<cos(2)theta> - 1/3) for pure heterodyne detection, where theta is the polar angle between the molecular axis and the laser polarization direction. Fourier transform spectra of the homodyne signal and the pure heterodyne signal were also studied. By comparing the alignment signal and its Fourier transform spectrum with the numerical calculation of the time-dependent Schrödinger equation, we demonstrated that the pure heterodyne signal directly reproduced the alignment parameter <cos(2)theta>, and its Fourier transform spectrum provided information regarding the populations of different J states in the rotational wavepacket.

References

Jun 5, 1995·Physical Review Letters·B Friedrich, D Herschbach
Oct 3, 2001·Physical Review Letters·F Rosca-Pruna, M J Vrakking
May 7, 2003·Physical Review Letters·V RenardH R Jauslin
Jul 15, 2003·Physical Review Letters·I V LitvinyukP B Corkum
Dec 17, 2004·Nature·J ItataniD M Villeneuve
Jan 15, 2005·Optics Letters·Vincent RenardBruno Lavorel
Jun 12, 2006·Optics Express·Nan XuQihuang Gong

❮ Previous
Next ❯

Citations

Jun 25, 2009·The Journal of Chemical Physics·Chengyin WuQihuang Gong
Sep 15, 2009·The Journal of Physical Chemistry. a·Chengyin WuQihuang Gong
Oct 12, 2019·The Journal of Physical Chemistry Letters·Wei ZhengChengyin Wu

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.