Mechanism and origins of regioselectivities of Rh-catalyzed alkenylation of allylbenzenes

Dalton Transactions : an International Journal of Inorganic Chemistry
Tian-Qi LiZheng-Yang Xu

Abstract

Rhodium-catalyzed alkenylation of allylbenzene derivatives via C-C bond activation provides an unprecedented access to alkenylation products with remarkable regioselectivities. Using DFT calculations, we elucidate the reaction mechanism and the origins of the regioselectivity.

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