Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Chemical Communications : Chem Comm
Richard C RemsingGuillermo Moyna

Abstract

13C and 35/37Cl NMR relaxation measurements on several model systems demonstrate that the solvation of cellulose by the ionic liquid (IL) 1-n-butyl-3-methylimidazolium chloride ([C4mim]Cl) involves hydrogen-bonding between the carbohydrate hydroxyl protons and the IL chloride ions in a 1 ratio 1 stoichiometry.

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Citations

Dec 7, 2011·Applied Microbiology and Biotechnology·Nele IlmbergerWolfgang R Streit
Dec 20, 2011·Interdisciplinary Sciences, Computational Life Sciences·Barmak MostofianXiaolin Cheng
Jul 24, 2013·Journal of Agricultural and Food Chemistry·André M da Costa LopesRafał Bogel-Łukasik
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