Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups

Dalton Transactions : an International Journal of Inorganic Chemistry
Subrata KunduKallol Ray

Abstract

Oxidation of phenols by heterodinuclear Cu(III)(μ-O)2Ni(III) complexes containing nucleophilic oxo groups occurs by both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms; the exact mechanism depends on the nature of the phenol as well as the substitution pattern of the ligand bound to Cu.

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Citations

Oct 21, 2015·Organic & Biomolecular Chemistry·Yanni YueRichard D Webster
Jan 20, 2017·Chemical Reviews·Courtney E ElwellWilliam B Tolman
Jan 26, 2017·Chemical Communications : Chem Comm·Evan E JoslinDavid P Goldberg
Aug 18, 2017·Chemistry : a European Journal·Frauke MöllerUlf-Peter Apfel
Jun 3, 2017·Chemical Science·Debanjan DharWilliam B Tolman
May 28, 2019·Journal of the American Chemical Society·Yexenia Nieves-QuinonesMarisa C Kozlowski
Mar 14, 2019·Inorganic Chemistry·Caitilín McManusAidan R McDonald
Jan 3, 2018·Journal of the American Chemical Society·Prasenjit MondalAidan R McDonald
Dec 6, 2019·Inorganic Chemistry·Duenpen UnjaroenAidan R McDonald
Jan 9, 2020·Journal of the American Chemical Society·Aditesh MondalSubrata Kundu
Oct 30, 2018·Chemical Reviews·Suzanne M AdamKenneth D Karlin

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