Mechanisms and kinetics of self-assembled monolayer formation

Annual Review of Physical Chemistry
Daniel K Schwartz

Abstract

Recent applications of various in situ techniques have dramatically improved our understanding of the self-organization process of adsorbed molecular monolayers on solid surfaces. The process involves several steps, starting with bulk solution transport and surface adsorption and continuing with the two-dimensional organization on the substrate of interest. This later process can involve passage through one or more intermediate surface phases and can often be described using two-dimensional nucleation and growth models. A rich picture has emerged that combines elements of surfactant adsorption at interfaces and epitaxial growth with the additional complication of long-chain molecules with many degrees of freedom.

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Citations

Dec 18, 2013·Bioelectrochemistry·Marta JarczewskaElżbieta Malinowska
Aug 21, 2013·Biosensors & Bioelectronics·Shengbo SangGang Li
Apr 5, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Yujin TongShen Ye
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Apr 12, 2013·The Journal of Chemical Physics·Xiao-Li FanWoon-Ming Lau
Jan 7, 2014·The Journal of Chemical Physics·Jan WeberEckart Hasselbrink
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Oct 6, 2015·Langmuir : the ACS Journal of Surfaces and Colloids·H-G SteinrückB M Ocko
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Feb 28, 2014·Angewandte Chemie·Steven E F KleijnPatrick R Unwin

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Methods Mentioned

BETA
X-ray
scanning tunneling microscopy
quartz crystal microbalance
surface plasmon resonance
atomic-force microscopy
AFM
atomic-force
scanning probe microscopy

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