Mechanistic Insights into Nanoparticle Formation from Bimetallic Metal-Organic Frameworks.

Journal of the American Chemical Society
Zhihengyu ChenKarena W Chapman

Abstract

Understanding and controlling nanomaterial structure, chemistry, and defects represents a synthetic and characterization challenge. Metal-organic frameworks (MOFs) have recently been explored as unconventional precursors from which to prepare nanomaterials. Here we use in situ X-ray pair distribution function analysis to probe the mechanism through which MOFs transform into nanomaterials during pyrolysis. By comparing a series of bimetallic MOFs with trimeric node different compositions (Fe3, Fe2Co, and Fe2Ni) linked by carboxylate ligands in a PCN-250 lattice, we demonstrate that the resulting nanoparticle structure, chemistry, and defect concentration depend on the node chemistry of the original MOF. These results suggest that the preorganized structure and chemistry of the MOF offer new potential control over the nanomaterial synthesis under mild reaction conditions. In the case of Fe2Ni-PCN-250, selective extraction of one Ni ion from each node without collapsing the framework (i.e., node-ligand connectivity) leaves a metal-deficient MOF state that may provide a new route to post-synthetically tune the chemistry the MOF and subsequent nanomaterials.

References

Jul 5, 2013·Journal of the American Chemical Society·Maolin PangMohamed Eddaoudi
Sep 15, 2016·Chemical Reviews·Alexander SchoedelOmar M Yaghi
Dec 10, 2016·Journal of the American Chemical Society·Omar M Yaghi
Apr 25, 2018·Journal of the American Chemical Society·Tiesheng WangStoyan K Smoukov
Oct 26, 2018·Journal of the American Chemical Society·Xiaolu WangYadong Li
Dec 18, 2018·ACS Applied Materials & Interfaces·Jia-Lu SunGuo-Ming Wang
Jun 12, 2019·Journal of the American Chemical Society·Christian SchneiderGregor Kieslich

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.