Mechanochemical Synthesis of Phosphazane-Based Frameworks

Chemistry : a European Journal
Ying SimFelipe García

Abstract

Mechanochemistry is emerging as a powerful solvent-free approach to chemical synthesis, having been applied to metal oxides, pharmaceutical materials, organic compounds and to a lesser extent, coordination complex synthesis. Notably, examples of applications of mechanochemical methodologies in the synthesis of main-group compounds are few and far between. Herein, we demonstrate that ball milling enabled the solvent-free synthesis of a range of phosphazane frameworks with a broad substrate scope, yielding seven new acyclic and macrocyclic species. The strength of this methodology is highlighted by a fast, selective and high-conversion product generation from poorly soluble starting materials, thereby demonstrating mechanochemistry as a real alternative to solution-based methods in synthetic main-group chemistry.

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Citations

Feb 6, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Madhusudan K PandeyMaravanji S Balakrishna
Feb 27, 2019·Chemical Society Reviews·Davin Tan, Felipe García
Oct 25, 2017·Beilstein Journal of Organic Chemistry·Agota A Gečiauskaitė, Felipe García
Jul 15, 2021·The Journal of Organic Chemistry·David VirieuxEvelina Colacino
Aug 21, 2018·Inorganic Chemistry·Yan X ShiFelipe García

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