Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis

Frontiers in Chemistry
Samer AbdulridhaXiaolei Fan

Abstract

Mesostructured zeolitic materials (MZMs) with relatively high acidity in comparison with the mesoporous siliceous MCM-41 were prepared via an efficient, mild, and simple post-synthetic treatment of Y zeolite facilitated by microwave irradiation, i.e., microwave-assisted chelation (MWAC). The disordered mesoporous aluminosilicates materials (DMASs) of MZM were created from Y zeolite in the absence of using mesoscale templates. The prepared DMASs showed the good mesoporous features with the mesopore area and volume of ~260 m2 g-1 and ~0.37 cm3 g-1, respectively, and with the mesopore sizes distributed in a range of 2-10 nm. MZMs possess a total acidity of about 0.6 mmol g-1 and exhibited comparatively superior catalytic activity to the parent Y zeolite and MCM-41 in the vapor phase catalytic dealkylation of 1,3,5-triisopropylbenzene (TiPBz) and liquid phase catalytic aldol condensation of benzaldehyde with 1-heptanal. Although the yield loss was inevitable for preparing MZMs using the MWAC method, the preliminary economic analysis of the preparation cost of MZMs showed the promise. Additionally, a comprehensive comparison of the state-of-the-art mesoporous materials concerning their sustainable aspects was made, showing that MZMs...Continue Reading

References

Jun 21, 2002·Nature·Mark E Davis
Sep 15, 2007·Angewandte Chemie·María Vallet-RegíDaniel Arcos
Nov 8, 2012·Chemical Society Reviews·Carlo Perego, Roberto Millini
Nov 10, 2012·Chemical Society Reviews·D P SerranoP Pizarro
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Jan 7, 2015·Nature Materials·Hussein AwalaSvetlana Mintova
Apr 14, 2015·Chemical Communications : Chem Comm·Teerawit PrasomsriJavier Garcia Martinez

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Methods Mentioned

BETA
nuclear magnetic resonance
X-ray
x-ray diffraction
chemical treatment

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