PMID: 30156746DOI: 10.1002/anie.201807592Aug 30, 2018Paper
Metal- and Oxidant-Free Alkenyl C-H/Aromatic C-H Cross-Coupling Using Electrochemically Generated Iodosulfonium Ions
Angewandte Chemie
Ryutaro HayashiJun-ichi Yoshida
Abstract
A three-step transformation consisting of 1) addition of electrochemically generated iodosulfonium ions to vinylarenes to give (1-aryl-2-iodoethoxy)sulfonium ions, 2) nucleophilic substitution by subsequently added aromatic compounds to give 1,1-diaryl-2-iodoethane, and 3) elimination of HI with a base to give 1,1-diarylethenes was developed. The transformation serves as a powerful metal- and chemical-oxidant-free method for alkenyl C-H/aromatic C-H cross-coupling.
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Citations
Jan 5, 2020·Chemistry : a European Journal·Yandong WangZhuangzhi Shi
Aug 16, 2019·Chemistry : a European Journal·Yosuke AshikariAiichiro Nagaki
Apr 10, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Fumitoshi Kakiuchi, Takuya Kochi
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