Metal-Free C(sp3 )-H Allylation via Aryl Carboxyl Radicals Enabled by Donor-Acceptor Complex

Organic Letters
Yang LiYiyun Chen

Abstract

The first aryl carboxyl radical generation by the donor-acceptor complex with N-acyloxyphthalimides and Hantzsch esters is reported. Regio- and chemoselective C(sp3)-H bond allylation is enabled by aryl carboxyl radicals with visible light irradiation under mild and metal-free conditions.

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Citations

Jul 4, 2019·Organic & Biomolecular Chemistry·Peng-Zi WangWen-Jing Xiao

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