Metal-organic coordination interactions in Fe-terephthalic acid networks on Cu(100)

Journal of the American Chemical Society
Steven L TaitKlaus Kern

Abstract

Metal-organic coordination interactions are prime candidates for the formation of self-assembled, nanometer-scale periodic networks with room-temperature structural stability. We present X-ray photoelectron spectroscopy measurements of such networks at the Cu(100) surface which provide clear evidence for genuine metal-organic coordination. This is evident as binding energy shifts in the O 1s and Fe 3p photoelectron peaks, corresponding to O and Fe atoms involved in the coordination. Our results provide the first clear evidence for charge-transfer coordination in metal-organic networks at surfaces and demonstrate a well-defined oxidation state for the coordinated Fe ions.

References

Jun 19, 2003·Angewandte Chemie·Alexandre DmitrievKlaus Kern
Sep 30, 2005·Nature·Johannes V BarthKlaus Kern
Mar 17, 2006·The Journal of Physical Chemistry. B·Sylvain ClairJohannes V Barth
Apr 28, 2006·Journal of the American Chemical Society·Ari P SeitsonenJohannes V Barth
Nov 17, 2006·The Journal of Physical Chemistry. B·Sebastian StepanowKlaus Kern
Feb 10, 2007·Chemistry : a European Journal·Dietmar PayerKlaus Kern
Sep 20, 2007·Journal of the American Chemical Society·Ken FlechtnerJ Michael Gottfried

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Citations

Dec 7, 2013·Nature Communications·Doris GrumelliKlaus Kern
Jun 18, 2009·Chemical Communications : Chem Comm·Alexander LangnerKlaus Kern
Jan 18, 2017·Chemical Reviews·Xavier BoujuAndré Gourdon
May 12, 2017·Chemical Communications : Chem Comm·Ryota SakamotoHiroshi Nishihara
Apr 19, 2017·Chemistry : a European Journal·Amalia RapakousiouHiroshi Nishihara
Jun 25, 2014·Journal of the American Chemical Society·Aneliia ShchyrbaLutz H Gade
Jul 4, 2015·Chemical Communications : Chem Comm·Thomas NijsThomas A Jung
Aug 19, 2015·Chemical Communications : Chem Comm·Tuan Anh PhamMeike Stöhr
Mar 29, 2014·Chemical Communications : Chem Comm·Revital KaminkerMilko E van der Boom
Jul 28, 2012·International Journal of Molecular Sciences·Chao LuBo Xu
Jun 30, 2018·Chemical Communications : Chem Comm·Joshua Lipton-DuffinJennifer MacLeod
Jul 5, 2018·Chemical Society Reviews·Meiting ZhaoHua Zhang
Jul 22, 2018·Chemistry : a European Journal·Christopher D TempasSteven L Tait
Nov 11, 2008·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Steven L TaitKlaus Kern
Oct 8, 2009·Physical Chemistry Chemical Physics : PCCP·Takayuki SuzukiKlaus Kern
Jul 2, 2009·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Stefan KuckRoland Wiesendanger
Feb 13, 2019·Chemistry : a European Journal·Tobias W MorrisSteven L Tait
Jun 22, 2019·Advanced Materials·Ryota SakamotoHiroshi Nishihara
Jun 8, 2013·ChemPlusChem·Mihyun LeeHaeshin Lee
Jul 30, 2019·Advanced Materials·Liang ChengZhuang Liu
Jul 1, 2017·Water Science and Technology : a Journal of the International Association on Water Pollution Research·Shi-Chuan WuJian-Hua Cheng
Apr 14, 2016·Chemistry : a European Journal·Ada Della PiaGiovanni Costantini
Nov 3, 2015·Small·José I UrgelJohannes V Barth
Jun 15, 2011·Chemical Society Reviews·Javier MéndezJosé A Martín-Gago
Jun 23, 2012·Physical Chemistry Chemical Physics : PCCP·Wenhua ZhangChristof Wöll
Jan 26, 2018·Physical Chemistry Chemical Physics : PCCP·B Quiroga ArgañarazH Ascolani
Apr 21, 2018·Chemical Science·Christopher D TempasSteven L Tait
Jul 4, 2012·Physical Chemistry Chemical Physics : PCCP·Thomas WaldmannR Jürgen Behm
Dec 12, 2018·Environmental Science and Pollution Research International·Lin-Ling YuJian-Hua Cheng
May 2, 2012·Physical Chemistry Chemical Physics : PCCP·Steven L TaitPeter Seidel
Aug 21, 2020·Chemical Communications : Chem Comm·P S DeimelF Allegretti
Nov 11, 2011·Chemical Communications : Chem Comm·Yeliang WangGiovanni Costantini
May 22, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·Wei JinJanice E Reutt-Robey
Oct 28, 2010·Journal of the American Chemical Society·Wei XuFlemming Besenbacher

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