Metal-organic framework and inorganic glass composites

Nature Communications
Louis LongleyThomas D. Bennett

Abstract

Metal-organic framework (MOF) glasses have become a subject of interest as a distinct category of melt quenched glass, and have potential applications in areas such as ion transport and sensing. In this paper we show how MOF glasses can be combined with inorganic glasses in order to fabricate a new family of materials composed of both MOF and inorganic glass domains. We use an array of experimental techniques to propose the bonding between inorganic and MOF domains, and show that the composites produced are more mechanically pliant than the inorganic glass itself.

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Citations

Feb 12, 2021·Journal of the American Chemical Society·Mengtan LiuJarad A Mason
Feb 19, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Louis LongleyThomas D Bennett
Oct 1, 2021·Nature Communications·Vahid NozariLothar Wondraczek

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Methods Mentioned

BETA
differential scanning calorimetry
Confocal microscopy
nuclear magnetic resonance
NMR
light microscopy
Bragg diffraction
electron microscopy
X-ray

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