Metal-organic framework gels and monoliths

Chemical Science
Jingwei HouThomas D Bennett

Abstract

The synthesis of metal-organic frameworks (MOFs) has, to date, largely been in the form of crystalline powders. However, interest in different physical morphologies of this class of materials is growing. In this perspective, we provide an overview of the structure, properties and applications of MOF monoliths. In particular, we explore the complex synthetic landscapes associated with MOF crystallization and discuss the synthetic factors leading to the formation of MOF gels, i.e. the precursor to sol-gel MOF monoliths. Finally, we provide our thoughts on the future development of this field, and attempt to highlight the importance of the MOF gel state in the discovery of new functional materials.

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Citations

Mar 14, 2020·Chemical Communications : Chem Comm·Rijia LinVicki Chen
Jun 20, 2020·Angewandte Chemie·Jingwei HouLianzhou Wang
May 26, 2020·Angewandte Chemie·Frederik HaaseStefan Wuttke
Nov 10, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Joshua M TuffnellSiân E Dutton
Dec 16, 2020·Chemical Society Reviews·Zixi KangSvetlana Mintova
Nov 10, 2020·Journal of Colloid and Interface Science·Fabrice LorignonDaniel Meyer
Apr 28, 2021·Journal of the American Chemical Society·Mark D AllendorfChristopher H Hendon
Mar 11, 2021·Angewandte Chemie·Mehran AmiriMay Nyman
Apr 21, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Adam F SapnikThomas D Bennett
Jul 7, 2021·Materials Science & Engineering. C, Materials for Biological Applications·Kun YanDong Wang

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Methods Mentioned

BETA
X-ray
transmission
scanning electron microscopy
NMR
transmission electron microscopy
electron microscopy

Software Mentioned

LaMer

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