Metal-organic frameworks with high capacity and selectivity for harmful gases.

Proceedings of the National Academy of Sciences of the United States of America
David BrittOmar M Yaghi

Abstract

Benchmarks have been established for the performance of six metal-organic frameworks (MOFs) and isoreticular MOFs (IRMOFs, which have the same underlying topology as MOF-5), MOF-5, IRMOF-3, MOF-74, MOF-177, MOF-199, and IRMOF-62, as selective adsorbents for eight harmful gases: sulfur dioxide, ammonia, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethylene oxide, and carbon monoxide. Kinetic breakthrough measurements are used to determine the calculated dynamic adsorption capacity of each "benchmark" MOF for each gas. The capacity of each MOF is compared to that of a sample of Calgon BPL activated carbon. We find that pore functionality plays a dominant role in determining the dynamic adsorption performance of MOFs. MOFs featuring reactive functionality outperform BPL carbon in all but one case and exhibit high dynamic adsorption capacities up to 35% by weight.

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Citations

Jan 11, 2014·Journal of Colloid and Interface Science·Svetlana Bashkova, Teresa J Bandosz
Oct 8, 2011·Chemical Reviews·Jian-Rong LiHong-Cai Zhou
Dec 30, 2011·Chemical Reviews·Kenji SumidaJeffrey R Long
Jan 24, 2013·Inorganic Chemistry·Zhangwen WeiHong-Cai Zhou
Oct 16, 2013·Inorganic Chemistry·Zulema Arcís-CastilloJosé A Real
May 21, 2010·Journal of the American Chemical Society·Norberto MasciocchiSilvia Bordiga
Oct 16, 2010·Journal of the American Chemical Society·Andrea CentroneT Alan Hatton
Sep 21, 2010·Journal of the American Chemical Society·Eric D BlochOmar M Yaghi
Jul 19, 2011·Journal of the American Chemical Society·Carmen MontoroJorge A R Navarro
Aug 13, 2011·Journal of the American Chemical Society·Eric D BlochJeffrey R Long
Feb 9, 2012·Journal of the American Chemical Society·Jason S Grosch, Francesco Paesani
Jan 14, 2012·Journal of the American Chemical Society·Jared B DecosteColin R Willis
Jun 7, 2012·Journal of the American Chemical Society·Satoshi HorikeSusumu Kitagawa
Feb 27, 2013·Journal of the American Chemical Society·Milind Madhusudan DeshmukhShigeyoshi Sakaki
Apr 15, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Austin C KizzieAdam J Matzger
Jul 16, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Camille PetitTeresa J Bandosz
Oct 6, 2011·Langmuir : the ACS Journal of Surfaces and Colloids·Camille PetitTeresa J Bandosz
Apr 23, 2009·Chemical Society Reviews·Jian-Rong LiHong-Cai Zhou
Feb 20, 2009·Chemical Communications : Chem Comm·Yong YanMartin Schröder
Oct 8, 2009·Chemical Communications : Chem Comm·Martin R LoheStefan Kaskel
Aug 27, 2009·Chemical Communications : Chem Comm·Ramanathan VaidhyanathanGeorge K H Shimizu
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Nov 3, 2010·Chemical Communications : Chem Comm·Yasutaka InubushiSusumu Kitagawa
Sep 28, 2010·Chemical Communications : Chem Comm·Sergio J Garibay, Seth M Cohen
Dec 2, 2009·Proceedings of the National Academy of Sciences of the United States of America·David BrittOmar M Yaghi
May 1, 2013·Acta Crystallographica. Section C, Crystal Structure Communications·Xiao-Hui Huang
Dec 15, 2010·International Journal of Molecular Sciences·Hiroshi KajiroHirofumi Kanoh
Mar 19, 2014·Journal of the American Chemical Society·Zheng Li, Hua Chun Zeng
Jan 19, 2016·Journal of Hazardous Materials·Yang ChenJiangfeng Yang

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