Metal-Organic Layers Catalyze Photoreactions without Pore Size and Diffusion Limitations

Chemistry : a European Journal
Ruoyu XuWenbin Lin

Abstract

Metal-organic frameworks (MOFs) have emerged as promising single-site solid catalysts for organic reactions. However, MOF catalysts suffer from pore size limitation and slow diffusion, which are detrimental for photoreactions. Metal-organic layers (MOLs) have unique ultrathin 2D monolayer structures and overcome pore size and diffusion limitations. Here, the synthesis of photoactive Zr-RuBPY MOL based on Zr-oxo clusters and [Ru(bpy)3 ]2+ -containing linkers is reported as well as its application in photocatalytic [2+2] cyclizations of enones and Meerwein addition reactions between aryl diazonium salts, styrenes, and nitriles.

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Citations

Jul 23, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Chunxia TanYan Liu
Aug 23, 2019·Advanced Materials·Amarajothi DhakshinamoorthyHermenegildo Garcia
Aug 17, 2020·Talanta·Bo RuanFang-Chang Tsai
Apr 2, 2020·Journal of the American Chemical Society·Yang SongWenbin Lin
Dec 31, 2020·ACS Central Science·Lingyun Cao, Cheng Wang
Oct 9, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Jonghyeon LeeMin Kim
Dec 8, 2021·Nanoscale·Mariya ZvaigzneIgor Nabiev

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