Metal-organic organopolymeric hybrid framework by reversible [2+2] cycloaddition reaction

Angewandte Chemie
In-Hyeok ParkJagadese J Vittal

Abstract

Organic polymers are usually amorphous or possess very low crystallinity. The metal complexes of organic polymeric ligands are also difficult to crystallize by traditional methods because of their poor solubilities and their 3D structures can not be determined by single-crystal X-ray crystallography owing to a lack of single crystals. Herein, we report the crystal structure of a 1D Zn(II) coordination polymer fused with an organic polymer ligand made in situ by a [2+2] cycloaddition reaction of a six-fold interpenetrated metal-organic framework. It is also shown that this organic polymer ligand can be depolymerized in a single-crystal-to-single-crystal (SCSC) fashion by heating. This strategy could potentially be extended to make a range of monocrystalline metal organopolymeric complexes and metal-organic organopolymeric hybrid materials. Such monocrystalline metal complexes of organic polymers have hitherto been inaccessible for materials researchers.

References

Feb 20, 2004·Journal of the American Chemical Society·Shinji NomuraMikiji Miyata
Aug 25, 2004·Langmuir : the ACS Journal of Surfaces and Colloids·Kenichi MorigakiTakahisa Taguchi
Oct 14, 2004·Journal of the American Chemical Society·Sang Beom LeeAlan J Russell
Nov 19, 2005·Science·Adrien P CôtéOmar M Yaghi
Apr 20, 2006·Journal of the American Chemical Society·Rui XuHolger Frauenrath
Dec 18, 2007·Journal of the American Chemical Society·Sahar RashidnadimiAllen J Bard
Jan 12, 2008·Chemical Communications : Chem Comm·Abdul Malik Puthan PeedikakkalJagadese J Vittal
Feb 20, 2008·Accounts of Chemical Research·Leonard R MacGillivrayIvan G Georgiev
Aug 8, 2008·Journal of the American Chemical Society·Sang Soo HanWilliam A Goddard
Aug 21, 2008·Accounts of Chemical Research·Joseph W LauherNancy S Goroff
Mar 14, 2009·Journal of the American Chemical Society·Fernando J Uribe-RomoOmar M Yaghi
Apr 23, 2009·Chemical Society Reviews·Jeffrey R Long, Omar M Yaghi
Apr 23, 2009·Chemical Society Reviews·Takashi UemuraSusumu Kitagawa
May 26, 2009·Journal of the American Chemical Society·Jong Won ChungSoo Young Park
Dec 3, 2010·Nature Chemistry·Satoshi HorikeSusumu Kitagawa
Sep 13, 2011·Chemical Communications : Chem Comm·María CastellanoJoan Cano
Jan 28, 2012·Chemical Reviews·Hong-Cai ZhouOmar M Yaghi
Mar 28, 2012·Chemical Communications : Chem Comm·Hiroshi SatoSusumu Kitagawa
May 1, 2012·Chemistry : a European Journal·Anjana ChanthapallyJagadese J Vittal
Jul 24, 2012·Chemical Society Reviews·Xiao FengDonglin Jiang
Dec 20, 2012·Journal of the American Chemical Society·Simon Rondeau-GagnéJean-François Morin
Mar 21, 2013·Nature Chemistry·Gaetano DistefanoSusumu Kitagawa
Sep 24, 2013·Nature Chemistry·Daniel BeaudoinJames D Wuest

❮ Previous
Next ❯

Citations

Dec 29, 2015·Journal of the American Chemical Society·Zhenjie ZhangSeth M Cohen
Oct 6, 2015·Journal of the American Chemical Society·Naba K NathPanče Naumov
Apr 4, 2017·Chemical Society Reviews·Takashi KitaoTakashi Uemura
Dec 14, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Fei Fei LiFeng Luo
Oct 29, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Biplab MannaSujit K Ghosh
Feb 2, 2018·Advanced Materials·Jina HaoBing Yan
Dec 17, 2014·Chemical Communications : Chem Comm·Cheng-Peng LiMiao Du
Dec 22, 2015·Chemical Communications : Chem Comm·Raghavender MedishettyJagadese J Vittal
Aug 26, 2014·Chemistry : a European Journal·Biplab MannaSujit K Ghosh
Sep 28, 2018·Chemical Communications : Chem Comm·Shuto MochizukiTakashi Uemura
May 16, 2014·Chemical Communications : Chem Comm·In-Hyeok ParkJagadese J Vittal
Jun 28, 2014·Chemical Society Reviews·Jie-Peng ZhangXiao-Ming Chen
Oct 30, 2015·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Ping XuHsing-Lin Wang
May 13, 2017·Materials Horizons·Tiesheng WangStoyan K Smoukov
Mar 13, 2020·Chemistry : a European Journal·Zheng WangCheng-Yong Su
Jul 28, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Fei-Long HuYan Mi
Feb 1, 2014·Chemical Communications : Chem Comm·In-Hyeok ParkJagadese J Vittal
Aug 2, 2017·Chemistry : a European Journal·Xiao-Min KangBin Zhao
Dec 1, 2016·ChemPlusChem·Aniket Chowdhury, Partha Sarathi Mukherjee
Mar 10, 2020·IUCrJ·In-Hyeok ParkJagadese J Vittal
Jul 22, 2014·Angewandte Chemie·Atchutarao Pathigoolla, Kana M Sureshan
Oct 25, 2017·Angewandte Chemie·Hendrik FrischChristopher Barner-Kowollik
Feb 2, 2021·Chemical Communications : Chem Comm·Wei-Chao SongXiao-Jun Zhao

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.