Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

Chemical Communications : Chem Comm
Christine SchiesAbhik Ghosh

Abstract

An inherently chiral metallocorrole has been resolved for the first time by means of HPLC on a chiral stationary phase. For the compound in question, a homoleptic tungsten biscorrole, the absolute configurations of the enantiomers were assigned using online HPLC-ECD measurements in conjunction with time-dependent CAM-B3LYP calculations, which provided accurate simulations of the ECD spectra.

References

Jul 23, 2003·Inorganic Chemistry·Christian BrücknerJeanette A Krause Bauer
Dec 25, 2003·Journal of the American Chemical Society·Erik SteeneAbhik Ghosh
Nov 30, 2006·Angewandte Chemie·Martin BröringMax C Holthausen
Jul 22, 2009·Inorganic Chemistry·Abraham B AlemayehuAbhik Ghosh
Aug 5, 2010·Inorganic Chemistry·Abraham B AlemayehuAbhik Ghosh
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Oct 30, 2014·Angewandte Chemie·Torsten BruhnGerhard Bringmann
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Jun 3, 2015·Chemical Communications : Chem Comm·Sandro JurinovichBenedetta Mennucci
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May 13, 2017·Chemical Communications : Chem Comm·Abraham B AlemayehuAbhik Ghosh

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Citations

Feb 25, 2021·Chemistry, an Asian Journal·Yogesh Kumar MauryaHiroyuki Furuta
Jul 24, 2021·Accounts of Chemical Research·Abraham B AlemayehuAbhik Ghosh
Feb 8, 2019·Inorganic Chemistry·Abraham B AlemayehuAbhik Ghosh
Jun 28, 2019·Accounts of Chemical Research·Sumit Ganguly, Abhik Ghosh

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