Metallocorroles as sensing components for gas sensors: remarkable affinity and selectivity of cobalt(III) corroles for CO vs. O2 and N2

Dalton Transactions : an International Journal of Inorganic Chemistry
Jean-Michel BarbeRoger Guilard

Abstract

Most commercially available CO detectors are based upon metal oxides or electrochemical cell technologies. None of these approaches use the selective adsorption of CO gas on a molecular complex. Conversely, cobalt(III) corroles can bind small gaseous molecules allowing them for an application as sensing components for gas detectors. Here we describe the ability of cobalt corroles to selectively coordinate carbon monoxide vs. dinitrogen and dioxygen. The coordination properties were determined in the solid state and the adsorption characteristics were compared to those of the reference compound (To-PivPP)Fe(1,2-Me2Im), known for its remarkable CO binding properties. The adsorption data evidence that the selectivity, affinity and capacity of the cobalt(III) corroles for CO are larger than those of the porphyrin complex. However, from a chemical point of view, the selectivity of cobalt(III) corroles for CO vs. O2 is infinite since these derivatives do not bind O2 while (To-PivPP)Fe(1,2-Me2Im) does with an M value (PO2(1/2)/PCO(1/2)) equal to 51. In this manuscript we also show that the affinity of cobalt(III) corroles for CO is closely related to the Lewis acid character of the central cobalt(III) ion and therefore to the nature o...Continue Reading

References

Oct 1, 1976·Proceedings of the National Academy of Sciences of the United States of America·J P CollmanK S Suslick
Mar 19, 1975·Journal of the American Chemical Society·J P CollmanW T Robinson
Nov 26, 1975·Journal of the American Chemical Society·J P CollmanK S Suslick
Jun 9, 2001·The Journal of Organic Chemistry·D T Gryko, K Jadach
Jun 30, 2001·The Journal of Organic Chemistry·R PaolesseR G Khoury
Dec 6, 2002·Organic Letters·Roger GuilardMariusz Tasior
Jan 30, 2003·Journal of the American Chemical Society·Atif MahammedZeev Gross
Apr 29, 2003·Inorganic Chemistry·Ryan M KretzerKenneth D Karlin
Aug 22, 2003·Organic & Biomolecular Chemistry·Daniel T Gryko, Beata Koszarna
May 17, 1999·Angewandte Chemie·Zeev GrossIrena Saltsman
Jun 1, 2001·Angewandte Chemie·Galina GolubkovZeev Gross

❮ Previous
Next ❯

Citations

Jan 9, 2013·Naunyn-Schmiedeberg's Archives of Pharmacology·Ali AlshehriMichel Félétou
Jan 22, 2009·Organic & Biomolecular Chemistry·Thien Huynh NgoWouter Maes
Sep 25, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Woormileela SinhaSanjib Kar
Mar 20, 2015·Chemistry : a European Journal·Gabriel CanardTeodor Silviu Balaban
Jul 21, 2006·Angewandte Chemie·Claude P GrosRoger Guilard
Oct 20, 2007·Chemistry : a European Journal·Yongshu XieKatsuhiko Ariga
Nov 20, 2009·Chemistry, an Asian Journal·Mariusz TasiorLucia Flamigni
Jul 11, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Stéphane BrandèsClaude P Gros
Dec 19, 2008·The Journal of Biological Chemistry·Kelly S DavidgeRobert K Poole
Aug 24, 2007·Chemical Communications : Chem Comm·Iris Aviv, Zeev Gross
Nov 8, 2017·Scientific Reports·Xia ShengLin Du
May 28, 2010·The Journal of Organic Chemistry·Vijayendra S ShettiMangalampalli Ravikanth
Nov 8, 2007·Inorganic Chemistry·Manuela StefanelliRoberto Paolesse
Jul 17, 2007·Organic Letters·Wouter MaesWim Dehaen
May 27, 2010·Inorganic Chemistry·Giuseppe PomaricoKarl M Kadish
Jul 13, 2021·European Journal of Organic Chemistry·Daniel TimelthalerChristoph Topf
Sep 26, 2006·Trends in Biochemical Sciences·Jorge BoczkowskiRoberto Motterlini
Apr 16, 2015·Inorganic Chemistry·Biju BasumataryJeyaraman Sankar
Jun 18, 2015·Organic Letters·Irena SaltsmanZeev Gross
Feb 23, 2017·Chemical Reviews·Roberto PaolesseCorrado Di Natale
May 27, 2020·Inorganic Chemistry·W Ryan OsterlohKarl M Kadish

❮ Previous
Next ❯

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Proceedings of the National Academy of Sciences of the United States of America
Hasmik AgadjanianLali K Medina-Kauwe
Journal of the American Chemical Society
Eli StavitskiHaim Levanon
The Journal of Organic Chemistry
Roberto PaolesseR G Khoury
© 2022 Meta ULC. All rights reserved