Metallophthalocyanin-ocenes: scandium phthalocyanines with an η(5)-bound Cp ring

Chemical Communications : Chem Comm
Rachel H PlatelDaniel B Leznoff

Abstract

A series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl3, which upon addition of LiCH(SiMe3)2 yields THF-soluble PcSc(μ-Cl2)Li(THF)2 (2). Metathesis with NaCp or LiCp* generates PcSc(η(5)-C5H5) and PcSc(η(5)-C5Me5), respectively, which represent the first examples of η(5)-Cp metal phthalocyanines where the Cp fragment sandwiches the metal centre.

References

Jan 16, 2003·Inorganic Chemistry·N KobayashiK Ishii
Aug 30, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Kimberly C JantunenDaniel B Leznoff
Aug 20, 2009·Chemical Society Reviews·Luciano Cuesta, Jonathan L Sessler
Sep 2, 2009·Journal of the American Chemical Society·Luciano CuestaJonathan L Sessler

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Citations

Jul 15, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Wen ZhouDaniel B Leznoff
Jan 11, 2018·Chemical Communications : Chem Comm·Wen Zhou, Daniel B Leznoff

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