Metallopolymeric films based on a biscyclometalated ruthenium complex bridged by 1,3,6,8-tetra(2-pyridyl)pyrene: applications in near-infrared electrochromic windows

Inorganic Chemistry
Chang-Jiang YaoYu-Wu Zhong

Abstract

A biscyclometalated ruthenium complex bridged by the 2,7-deprotonated form of 1,3,6,8-tetra(2-pyridyl)pyrene was deposited onto indium-tin oxide glass electrodes by reductive electropolymerization. The resulting metallopolymeric films exhibited tricolor electrochromic behavior in the near-infrared region upon switching of the two well-separated Ru(II/III) processes at low potentials. A good contrast ratio (35%) at 2050 nm and a long memory time up to 100 min were recorded for this electrochromic behavior. The response time is typically of a few seconds.

References

Jun 24, 2003·Inorganic Chemistry·Matteo BiancardoCarlo Alberto Bignozzi
Oct 26, 2005·Chemical Communications : Chem Comm·Gursel Sonmez
Mar 12, 2009·Journal of the American Chemical Society·Leila MotieiMilko E van der Boom
Jan 15, 2010·Chemical Reviews·Pierre M Beaujuge, John R Reynolds
Mar 31, 2010·Chemistry, an Asian Journal·Gang Qian, Zhi Yuan Wang
Jul 9, 2010·Journal of the American Chemical Society·Adam B PowellAlan H Cowley

❮ Previous
Next ❯

Citations

Nov 7, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Biswa Nath GhoshKari Rissanen
Dec 13, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Jiang-Yang ShaoYu-Wu Zhong
Jul 13, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Amit SilSanjib K Patra
Feb 9, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Jian-Hong TangYu-Wu Zhong
Jul 6, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·You-Ming ZhangYu-Wu Zhong
Dec 7, 2018·Chemical Society Reviews·Yanlan WangAlaa S Abd-El-Aziz
Jan 25, 2014·Chemistry : a European Journal·Christian FriebeUlrich S Schubert
Oct 21, 2020·Chemical Society Reviews·Guojian YangSean Xiao-An Zhang
Sep 11, 2019·Langmuir : the ACS Journal of Surfaces and Colloids·Hong YinShu-Yan Yu

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.