Metallopolymers cross-linked with self-assembled Ln4 L4 cages

Dalton Transactions : an International Journal of Inorganic Chemistry
Qian-Qian YanQing-Fu Sun

Abstract

Herein, we fabricated a hybrid PDVB-Ln4L4 metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

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Citations

May 16, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jorge Salinas-UberGuillem Aromí
Nov 18, 2020·Chemistry : a European Journal·Yong-Kai DengLan-Sun Zheng

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Methods Mentioned

BETA
NMR
scanning electron microscopy
dynamic light scattering

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