Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2 C2 B8 Me8 (R = H and Me) and their monosubstituted analogues

Dalton Transactions : an International Journal of Inorganic Chemistry
Mario BakardjievBohumil Štíbr

Abstract

Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta - decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.

References

Jul 21, 2005·Journal of the American Chemical Society·Francesc TeixidorClara Viñas
May 4, 2006·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Jindrich FanfrlíkPavel Hobza
Dec 15, 2006·Chemical Reviews·Stefanie KörbeJosef Michl
Dec 30, 2014·Acta Crystallographica. Section A, Foundations and Advances·George M Sheldrick
Jun 29, 2016·Inorganic Chemistry·Mario BakardjievAleš Růžička
Jan 26, 2017·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Catharine EsterhuysenTimothy Clark
May 31, 2017·Physical Chemistry Chemical Physics : PCCP·Jindřich FanfrlíkPavel Hobza
Jan 13, 2018·Physical Chemistry Chemical Physics : PCCP·Petr MelicharJindřich Fanfrlík

❮ Previous
Next ❯

Methods Mentioned

BETA
NMR
X-ray

Software Mentioned

Molekel4
XT
Gaussian09
Bruker SAINT
SHELXL

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Advancement of Science
H B COTT
General Dentistry
R D Winland
The Australasian Journal of Dermatology
M Downie
Surgery, Gynecology & Obstetrics
R Graham, J Graham
© 2022 Meta ULC. All rights reserved