Mild benzene-thermal route to GaP nanorods and nanospheres

Inorganic Chemistry
Shanmin GaoMinhua Jiang

Abstract

GaP nanorods and nanospheres were synthesized from a mild benzene-thermal route at 240 and 300 degrees C, respectively, using Na, P, and GaCl(3) as the starting materials. The structure of the products was identified as zinc blende phase by X-ray powder diffraction (XRD). Transmission electron microscopy (TEM) images showed that, when the reaction temperature was 240 degrees C, the products were nanorods with widths of 20-40 nm and lengths of 200-500 nm and nanospheres with diameters of 20-40 nm. However, when the reaction temperature was increased to 300 degrees C, the products were only nanospheres, and the diameters increased to 40-60 nm. The reaction proceeded through a metallic gallium intermediate, and a solution-liquid-solid (SLS) mechanism was proposed for the one-dimensional growth. The products were also investigated by UV-vis absorption and X-ray photoelectron spectroscopy.

References


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Citations

Jul 21, 2006·The Journal of Physical Chemistry. B·Qiang WuYinong Lu
Mar 6, 2007·Ultrasonics Sonochemistry·Zhengrong Li, Dominick J Casadonte

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