Mineral N stock and nitrate accumulation in the 50 to 200m profile on the Loess Plateau

The Science of the Total Environment
Xiaoxu JiaMingan Shao

Abstract

Nitrogen (N) stored in deep profiles is important in assessing regional and/or global N stocks and nitrate leaching risk to groundwater. The Chinese Loess Plateau, which is characterized by significantly thick loess deposits, potentially stores immense stocks of mineral N, posing future threats to groundwater quality. In order to determine the vertical distributions of nitrate and ammonium content in the region, as well as to characterize the potential accumulation of nitrate in the deep loess profile, we study loess samples collected at five sites (Yangling, Changwu, Fuxian, An'sai and Shenmu) through a 50 to 200m loess profile. The estimated storage of mineral N varied significantly among the five sites, ranging from 0.46 to 2.43×104kgNha-1. Ammonium exhibited fluctuations and dominated mineral N stocks within the whole profile at the sites, except for the upper 20-30m at Yangling and Changwu. Measured nitrate content in the entire profile at Fuxian, An'sai and Shenmu is low, but significant accumulations were observed to 30-50m depth at the other two sites. Analysis of δ15N and δ18O of nitrate indicates different causes for accumulated nitrate at these two sites. Mineralization and nitrification of manure and organic N respe...Continue Reading

Citations

Apr 2, 2021·The Science of the Total Environment·Matthew J AscottBen W J Surridge
Apr 14, 2021·Environmental Science & Technology·Jingbo GaoJianbin Zhou
Nov 3, 2021·Environmental Science and Pollution Research International·Yue DongGan-Lin Zhang

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