Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions

Dalton Transactions : an International Journal of Inorganic Chemistry
Alexandra A AgeshinaMaxim V Bermeshev

Abstract

A series of novel (NHC)PdCl2-PR3 complexes were synthesized and fully characterized by 1H, 13C, 31P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable N-aryl carbazoles and similar N-heterocyclic systems was described.

References

May 18, 2000·The Journal of Organic Chemistry·J P Wolfe, S L Buchwald
Sep 25, 2004·Organic Letters·Michał J ChmielewskiJanusz Jurczak
Mar 25, 2005·The Journal of Organic Chemistry·Hidehiro SakuraiToshikazu Hirao
Jul 14, 2006·Chemical Reviews·Jean-Pierre Corbet, Gérard Mignani
Apr 13, 2007·Chemical Reviews·Yasuhiko Shirota, Hiroshi Kageyama
Jun 15, 2007·The Journal of Organic Chemistry·T Daniel ThangaduraiKwang S Kim
Sep 15, 2007·Nature Reviews. Drug Discovery·Alfonso Quintás-CardamaJorge Cortes
Apr 12, 2008·Organic Letters·Akiko UenoNoritaka Chida
Dec 17, 2008·Chemical Communications : Chem Comm·Ting QiDaoben Zhu
Dec 25, 2009·The Journal of Organic Chemistry·Artem A KulagoBen L Feringa
Jun 15, 2010·Angewandte Chemie·Aron PintérMartin Klussmann
Aug 18, 2010·Angewandte Chemie·Thomas Dröge, Frank Glorius
Dec 1, 2010·Chemical Communications : Chem Comm·Eleanor M HigginsAnnMarie C O'Donoghue
Apr 21, 2011·Journal of Medicinal Chemistry·Stephen D Roughley, Allan M Jordan
Jun 1, 2011·Chemical Communications : Chem Comm·Thibault E SchmidCatherine S J Cazin
Apr 7, 2012·Chemical Reviews·Arndt W SchmidtHans-Joachim Knölker
Dec 21, 2012·Chemical Communications : Chem Comm·Caroline E HartmannCatherine S J Cazin
Jan 26, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Thibault E SchmidCatherine S J Cazin
Nov 16, 2013·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Mi-Seon SongKyu Yun Chai
Jun 11, 2016·Chemical Reviews·Nathan A Romero, David A Nicewicz
Oct 14, 2016·Organic Letters·Sean W Reilly, Robert H Mach
Mar 17, 2017·Chemistry : a European Journal·Maxim A TopchiySergey N Osipov
Apr 20, 2017·Journal of Medicinal Chemistry·Andrew C FlickChristopher J O'Donnell
Nov 9, 2017·Organic & Biomolecular Chemistry·Pavel S GribanovMikhail S Nechaev
Dec 7, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ming-Tsz Chen, Zing-Lun Kao
Sep 5, 2018·Organic Letters·Shiyang XuZhenhua Zhang
Sep 19, 2018·Organic & Biomolecular Chemistry·Qun CaoDuncan L Browne
Jan 12, 2019·Nature Communications·Koji KubotaHajime Ito

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Citations

Jan 22, 2021·Chemical Society Reviews·Fady Nahra, Catherine S J Cazin
Jan 19, 2021·RSC Advances·Nathaniel GeorgeSamuel G Awuah
May 13, 2021·Chemical Communications : Chem Comm·Sergey A RzhevskiyAndrey F Asachenko
Jul 14, 2021·The Journal of Organic Chemistry·Volodymyr SemeniuchenkoMichael G Organ
Jul 1, 2021·Chemistry : a European Journal·Volodymyr SemeniuchenkoMichael G Organ

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