Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes

Dalton Transactions : an International Journal of Inorganic Chemistry
Benjamin M DayRichard A Layfield

Abstract

Two dysprosium complexes, [(C5H4Me)2Dy(L(1))] (3) and [(L(1))Dy(μ-Cl)3{Li(tmeda)}]2 (4), with amino-functionalized pentadienyl ligands L(1) are described. Crystallographic studies of 3 and 4 show that the pendant amino group influences the pentadienyl conformation and the ligand hapticity. Electronic structure calculations reveal that L(1) has a strong influence on the orientation of the main magnetic axis of the ground Kramers doublets in 3 and 4.

References

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Mar 22, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthias ReinersMarc D Walter

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Citations

Aug 25, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Ann Christin FeckerMarc D Walter
Oct 19, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Jin ZhangYaping Dong
Sep 8, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jan RaederMarc D Walter
May 21, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Ann Christin FeckerMarc D Walter
May 29, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Alexandros MortisReiner Anwander
May 13, 2021·Chemistry : a European Journal·Jochen JungDietmar Stalke

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