Molecular and Supramolecular Multiredox Systems.

ChemistryOpen
Jyoti ShuklaPritam Mukhopadhyay

Abstract

The design and synthesis of molecular and supramolecular multiredox systems have been summarized. These systems are of great importance as they can be employed in the next generation of materials for energy storage, energy transport, and solar fuel production. Nature provides guiding pathways and insights to judiciously incorporate and tune the various molecular and supramolecular design aspects that result in the formation of complex and efficient systems. In this review, we have classified molecular multiredox systems into organic and organic-inorganic hybrid systems. The organic multiredox systems are further classified into multielectron acceptors, multielectron donors and ambipolar molecules. Synthetic chemists have integrated different electron donating and electron withdrawing groups to realize these complex molecular systems. Further, we have reviewed supramolecular multiredox systems, redox-active host-guest recognition, including mechanically interlocked systems. Finally, the review provides a discussion on the diverse applications, e. g. in artificial photosynthesis, water splitting, dynamic random access memory, etc. that can be realized from these artificial molecular or supramolecular multiredox systems.

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Citations

Feb 19, 2021·Journal of the American Chemical Society·Sudhir Kumar KeshriMasayuki Takeuchi
Jun 16, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Hiroyuki Ueda, Soichiro Yoshimoto

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Methods Mentioned

BETA
Differential Pulse Voltammetry
light harvesting
biosensor
quartz crystal microbalance

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