Mono- and dinuclear tetraphosphabutadiene ferrate anions

Dalton Transactions : an International Journal of Inorganic Chemistry
Uttam ChakrabortyRobert Wolf

Abstract

Reduction of [CpArFe(μ-Br)]2(1, CpAr= C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe(η4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42-ligand. The related diiron complex [Na2(THF)5(CpArFe)2(μ,η4:4-P4)] (3) was obtained by reducing 1 with sodium amalgam in the presence of P4. Protonation of 3 affords [Na(THF)3][(CpArFe)2(μ,η4:4-P4)(H)] (4), while the reaction of 3 with trimethylchlorosilane gives the nortricyclane compound P7(SiMe3)3as the main product.

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Citations

Oct 2, 2019·Angewandte Chemie·Christian M HoidnRobert Wolf
Sep 29, 2019·Angewandte Chemie·Anup K AdhikariRobert Wolf
Aug 4, 2020·Zeitschrift für anorganische und allgemeine Chemie·Christoph G P ZieglerRobert Wolf
Sep 22, 2020·Angewandte Chemie·Christoph RiesingerManfred Scheer
Aug 4, 2020·Chemistry : a European Journal·Manfred ScheerStefano Todisco
Nov 3, 2020·Chemistry : a European Journal·Christian M HoidnRobert Wolf
Feb 3, 2021·Chemical Communications : Chem Comm·Julian MüllerManfred Scheer
Jun 1, 2021·Organometallics·Marion TillOliver Reiser
Jun 8, 2021·Chemical Science·Martin PieschManfred Scheer

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Methods Mentioned

BETA
NMR
X-ray

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