Monoorganooxotin cage, diorganotin ladders, diorganotin double chain and triorganotin single chain formed with phosphonate and arsonate ligands

Dalton Transactions : an International Journal of Inorganic Chemistry
Yun-Peng XieMin-Zhong Su

Abstract

The solvothermal reaction of n-BuSn(O)OH with PhPO(3)H(2) afforded the hexanuclear monoorganooxotin phosphonate cage, {[(n-BuSn)(3)(MeO)(3)O](2)(O(3)PPh)(4)}.MeOH 1. When the n-Bu(2)Sn(PhCO(2))(2) precursor reacted with PhPO(3)H(2) in a 1 : 1 stoichiometric ratio, the diorganotin phosphonate ladder [n-Bu(2)SnO(3)PPh](n) 2 was obtained. The reaction of [n-Bu(2)(PrO)Sn](2)O with 4-OH-3-NO(2)-C(6)H(3)AsO(3)H(2) affords the diorganotin arsonate ladder [n-Bu(2)Sn(4-OH-3-NO(2)-C(6)H(3)AsO(3))](n) 3, while the reaction of [n-Bu(2)(PrO)Sn](2)O with 4-NO(2)-C(6)H(4)AsO(3)H(2) and 4-Me-C(6)H(4)SO(3)H gives an diorganotin double chain [n-Bu(2)Sn(4-Me-C(6)H(4)SO(3))(4-NO(2)-C(6)H(4)AsO(3)H)](n) 4, which contains both sulfonate and arsonate ligands. The reaction of 4-NO(2)-C(6)H(4)AsO(3)H(2), EtONa, and Ph(3)SnCl yields a new triorganotin arsonate single chain [(Ph(3)Sn)(4)(4-NO(2)-C(6)H(4)AsO(3))(2).H(2)O](n) 5. The NMR ((1)H, (13)C, (119)Sn) spectra of compounds 1 and 4 were studied.

References

Feb 27, 2003·Journal of the American Chemical Society·Vadapalli ChandrasekharJagadese J Vittal
Apr 29, 2004·Angewandte Chemie·Guo-Li ZhengJing-Fu Liu
May 19, 2004·Accounts of Chemical Research·Junzo Otera
Feb 24, 2005·Journal of the American Chemical Society·Vadapalli ChandrasekharG Narahari Sastry
Jul 9, 2005·Chemistry : a European Journal·Vadapalli ChandrasekharJamie F Bickley
Apr 19, 2007·Accounts of Chemical Research·Vadapalli ChandrasekharPakkirisamy Thilagar
Mar 13, 2008·Chemistry : a European Journal·Yun-Peng XieZhong-Min Su

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Citations

Mar 29, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Monika KořenkováLibor Dostál
Jan 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Jie GongTeng-Feng Xie
Sep 7, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiao XiaoLin Xu
Jun 30, 2015·Chemical Reviews·Joydeb Goura, Vadapalli Chandrasekhar
Nov 29, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiang-Ying QianJiang-Gao Mao
Jun 25, 2016·Journal of Inorganic Biochemistry·Susanta HazraArmando J L Pombeiro
Aug 29, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun-Ling JinXing Lu
May 5, 2018·Acta Crystallographica. Section C, Structural Chemistry·Abdel Fattah ShihadaWerner Massa

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