PMID: 11308671Apr 20, 2001Paper

Monte Carlo simulation of morphologies of self-assembled amphiphilic diblock copolymers in solution

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
Xuehao HeC Pan

Abstract

The Monte Carlo method has been applied to simulate the process of the self-assembling of amphiphilic diblock copolymers in a selective solvent. The simulations illustrated that the aggregates morphologies of A-b-B diblock copolymers in solution strongly depend on the length of corona-forming segments, i.e., with the decrease of the corona-forming segments, the transition of spherical micelles to rodlike aggregates occurs, which are in accord with the experimental results of Eisenberg and co-workers [Science 268, 1728 (1995); Macromolecules 32, 2239 (1999); 31, 3509 (1998); 29, 6359 (1996); 31, 9399 (1998)].

Citations

Mar 19, 2014·The Journal of Chemical Physics·Asfaw Gezae Daful, Allan D Mackie
Jun 11, 2005·The Journal of Chemical Physics·Pingchuan SunAn-Chang Shi
Sep 28, 2004·Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics·Domenico LombardoMikhail A Kiselev
Jan 9, 2017·Polymers·Ali GooneieClemens Holzer

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