(Multi-)Metallic Cluster Growth

Chemistry : a European Journal
Bastian WeinertStefanie Dehnen

Abstract

This review article provides a survey of contemporary investigations on main group metal cluster formation, addressing homo- and heterometallic clusters (including small numbers of transition metal atoms), with or without an external ligand shell, thereby excluding clusters with non-metal atoms as bridging ligands. Most of the studies reflected herein represent insights into the formation of intermediates from the starting material, or the final cluster formation from established intermediates. In rare cases, the entire process was suggested as a result of comprehensive, multi-method elucidations. The article is to be understood as a state-of-the-art report, as the subject matter is currently a rising field of research, which is still in its infancy, despite some early activities that date back to the 1980s. At the same time, the article intends to point toward both the importance and the feasibility of according studies, in order to encourage researchers to gain even more knowledge in this field. Only deep understanding of cluster formation will allow for design, and ultimately control, of their syntheses, with the long-term goal of their optimization and purposeful application in catalysis or novel material synthesis.

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Citations

Sep 22, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Robert J WilsonStefanie Dehnen
Aug 12, 2018·Angewandte Chemie·Kerstin MayerRoland A Fischer
May 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·C WallachT F Fässler
Feb 29, 2020·Chemical Science·Bertram PetersStefanie Dehnen
Apr 28, 2021·Journal of the American Chemical Society·Fuxing PanStefanie Dehnen
Apr 30, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Aleksandra V PaderinaElena V Grachova
Jun 29, 2021·Chemical Communications : Chem Comm·Oliver P E TownrowJose M Goicoechea
Oct 6, 2020·Inorganic Chemistry·Felix S Geitner, Thomas F Fässler
Oct 28, 2021·Chemical Reviews·Alexander V VirovetsManfred Scheer
Nov 3, 2021·Chemical Society Reviews·Susan M KauzlarichJesse Lundervold
Dec 22, 2021·Chemical Society Reviews·John E McGradyStefanie Dehnen

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