Multicenter bonding in carbocations with tetracoordinate protons

The Journal of Physical Chemistry. a
Robert PonecDean J Tantillo

Abstract

The nature of the bonding in a set of nonclassical carbocations with tetracoordinated protons "sandwiched" between two C=C pi bonds was scrutinized using the new computational methodology of generalized population analysis. The results of this theoretical analysis strongly corroborate the conclusions of a previous study in which the occurrence of delocalized 5-center 4-electron (5c-4e) bonding in the C-C-H-C-C fragments of such cations was anticipated.

References

Aug 31, 2002·Angewandte Chemie·Thomas Müller
Apr 3, 2003·Journal of the American Chemical Society·Dean J Tantillo, Roald Hoffmann
Oct 11, 2003·The Journal of Organic Chemistry·Robert Ponec, Gleb Yuzhakov
Apr 12, 2005·Angewandte Chemie·Pradeep Gutta, Dean J Tantillo
Jul 13, 2006·The Journal of Physical Chemistry. a·Robert PonecAna Gallegos Saliner

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Citations

Jul 18, 2012·Physical Chemistry Chemical Physics : PCCP·Jason G Harrison, Dean J Tantillo
Mar 19, 2013·Beilstein Journal of Organic Chemistry·Quynh Nhu N Nguyen, Dean J Tantillo
Jan 12, 2017·Chemical Communications : Chem Comm·Ravindra K Raut, Moumita Majumdar
Jul 29, 2008·Journal of Bacteriology·Sean A AggerClaudia Schmidt-Dannert
Mar 13, 2015·Journal of the American Chemical Society·Young J Hong, Dean J Tantillo
Dec 5, 2019·The Journal of Organic Chemistry·Yi Wang, Zhi-Xiang Yu
May 4, 2006·Journal of the American Chemical Society·Pradeep Gutta, Dean J Tantillo

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